کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8022943 1517416 2018 127 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Interdiffusion along grain boundaries - Diffusion induced grain boundary migration, low temperature homogenization and reactions in nanostructured thin films
ترجمه فارسی عنوان
تبخیر درون مرزهای دانه - مهاجرت مرزهای دانه ناشی از پراکندگی، همگن سازی دمای پایین و واکنش در فیلم های نازک نانوساختار
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
چکیده انگلیسی
Interdiffusion along grain boundaries can lead to shift of grain boundaries in form of Grain Boundary Diffusion Induced Grain Boundary Migration, DIGM, in systems forming wide range solid solutions, and to the Grain Boundary Diffusion Induced Solid State Reactions, in systems containing intermetallic phases. If, during above processes, the grain size of the sample is smaller than the double of the migration distance complete homogenization can also be reached (cold homogenization). Atomic mechanisms and phenomenological description of such alloying are reviewed. The main driving force, at low temperatures where the bulk diffusion is completely frozen out, arises from the unequality of the grain boundary atomic fluxes, leading to stress accumulations. The cold homogenization is the manifestation of such stress relaxations. Reviewing experimental data, we illustrate that DIGM takes place on both sides of a binary AB thin film and the solute content in the DIGM zone is higher on the side of the component of higher melting point (i.e. in the slower component). In binary systems containing intermetallic compounds the cold homogenization can lead, either to the formation of a given stoichiometric compound, or to two phase equilibrium, in accordance with the phase diagram. Different possible applications are likewise surveyed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Progress in Materials Science - Volume 98, October 2018, Pages 625-674
نویسندگان
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