کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8039068 | 1518592 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of He ion irradiation on the microstructure of tâ² phase yttria-stabilized zirconia ceramic coatings
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سطوح، پوششها و فیلمها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Yttria-stabilized zirconia (YSZ) films with tetragonal (tâ²) phase was prepared on China Low Activation Martensitic steel (CLAMs) substrates by supersonic atmospheric plasma spraying (SAPS) with ZrO2-8â¯wt% Y2O3 nano-powders as feedstock. This study deals with the subject of the structural modifications and phase transformations in tâ² phase YSZ coatings induced by implantation of low-energy (60â¯keV) He ions. It is found that the phase transformation in tâ² phase YSZ coatings during helium ion-irradiation as a function of fluence can be divided into a two-stage process based on the microstructural evolution as follows: (i) In the case of He ions at 0.5â¯Ãâ¯1017â¯cm2 (â¼1.5â¯dpa), no obvious volume swelling can be detected, suggesting the irradiation-induced defects is primarily associated with a positive relaxation volume. Therefore, only tâ²â¯ââ¯t phase transformation was observed for the samples implanted at a fluence of 0.5â¯Ãâ¯1017â¯cmâ2. (ii) While increasing the fluence from 0.5â¯Ãâ¯1017â¯cmâ2 to 2â¯Ãâ¯1017â¯cmâ2, an increase in the defect concentrations can be observed, leading to an exponential growth in volume swelling from 3.2% to 9.7% observed. These high- density extended defects can induce a plastic deformation in the lattice structure, resulting significant lateral compressive stress. Correspondingly, the tâ²â¯ââ¯tâ¯+â¯c phase transformation was detected for the samples implanted at the fluence of 2â¯Ãâ¯1017â¯cmâ2. At a fluence of 10â¯Ãâ¯1017â¯cmâ2, the formation of the He bubbles, and ellipsoidal cavities can be observed by TEM, inducing the further volume swelling. Meanwhile, the intensity of (4 0 0)c peak increases while fluence increase from 2â¯Ãâ¯1017â¯cmâ2 to 10â¯Ãâ¯1017â¯cmâ2. Based on the experimental results, a reasonable mechanism for the phase transformation of tâ² phase YSZ samples during He ions irradiation is proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms - Volume 431, 15 September 2018, Pages 67-73
Journal: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms - Volume 431, 15 September 2018, Pages 67-73
نویسندگان
Bo Liu, Jianxiong Zou, Liwei Lin, Shanlin Wang, Yu Bai, Chunhai Liu, Qiran Li,