کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8091319 1521994 2014 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Source term modeling for evaluating the potential impacts to groundwater of fluids escaping from a depleted oil reservoir used for carbon sequestration
ترجمه فارسی عنوان
مدل سازی دوره منبع برای ارزیابی اثرات بالقوه آب های زیرزمینی مایعات که از یک مخزن نفت تخلیه شده استفاده می شود برای جداسازی کربن
موضوعات مرتبط
مهندسی و علوم پایه علوم زمین و سیارات فرآیندهای سطح زمین
چکیده انگلیسی
Partitioning of organic compounds between crude oil and supercritical CO2 was modeled using the Peng-Robinson equation of state over temperature and pressure conditions that represent the entire subsurface system of the scenario under investigation (from those relevant to deep geologic carbon storage environments to near surface conditions). Results indicate that for the modeled oil reservoir conditions (75 °C, and 21,520 kPa) negligible amounts of the COI dissolve into the aqueous phase. When CO2 is introduced into the reservoir such that the final composition of the reservoir is 90 wt.% CO2 and 10 wt.% oil, a significant fraction of the oil dissolves into the vapor phase. As the vapor phase moves up through the stratigraphic column, pressures and temperatures decrease, resulting in significant condensation of oil components. The heaviest organic components condense early in this process (at higher pressures and temperatures), while the lighter components tend to remain in the vapor phase until much lower pressures and temperatures are reached. Based on the model assumptions, the final concentrations of COI to reach an aquifer at 1520 kPa and 25 °C were quite significant for benzene and toluene, whereas the concentrations of polynuclear aromatic hydrocarbons that reach the aquifer were very small. This work demonstrates a methodology that can provide COI source term concentrations in CO2 leaking from a reservoir and entering an overlying aquifer for use in risk assessments.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Greenhouse Gas Control - Volume 27, August 2014, Pages 139-145
نویسندگان
, ,