کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8094589 | 1522061 | 2018 | 27 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Highly mesoporous activated carbon synthesized by pyrolysis of waste polyester textiles and MgCl2: Physiochemical characteristics and pore-forming mechanism
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Activation-pyrolysis of textile wastes was considered a sustainable technique to fabricate activated carbon. Highly mesoporous activated carbon was prepared from waste polyester textiles by employing MgCl2 as the activation and template agents. The influences of different preparation conditions on textual property and crystalline structure of carbon were identified by N2 adsorption-desorption isotherms and X-ray diffraction. The optimum pyrolysis temperature, time and mixing ratio for MgCl2/waste polyester textiles are 900â¯Â°C, 1.5â¯h and 5:5 with the carbon thus obtained manifested a surface area of 1307â¯m2/g, total pore volume of 3.56â¯cm3/g of which 98% is mesopore. The effect of MgCl2 on the full-cycle pyrolysis pathway of waste polyester textiles was systematically investigated by various characterization methods to explore the pore-forming mechanism of activated carbon. The results demonstrated that MgCl2 was capable of catalyzing the dehydrogenation, decarboxylic and cross-linking reaction of waste polyester textiles and inhibited the formation of tars during pyrolysis process, indicating that the addition of MgCl2 was conducive to the formation of carbonaceous materials and open pores. Meanwhile, acted as the template, MgO particles derived from the decomposition of MgCl2 could develop massive homogeneous mesopores in the carbon matrix.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Cleaner Production - Volume 192, 10 August 2018, Pages 453-461
Journal: Journal of Cleaner Production - Volume 192, 10 August 2018, Pages 453-461
نویسندگان
Zhihua Xu, Zhihang Yuan, Daofang Zhang, Weifang Chen, Yuanxing Huang, Tianqi Zhang, Danqi Tian, Haixuan Deng, Yuwei Zhou, Zhenhua Sun,