کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8096444 1522068 2018 18 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Novel treatments for compatibility of plant fiber and starch by forming new hydrogen bonds
ترجمه فارسی عنوان
درمان های جدید برای سازگاری فیبر گیاهی و نشاسته با تشکیل اوراق قرضه هیدروژنی جدید
کلمات کلیدی
کامپوزیت زیست تخریب پذیر، فیبر گیاهی، نشاسته، سازگاری، پیوند هیدروژنی،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
چکیده انگلیسی
Cross-reaction of oxidization and plasticization was employed to prepare thermoplastic oxidized starch (TPOS). Oxidized ureal plant fiber (OUF) was prepared by soaking the plant fiber in H2O2 and treating it with urea at low temperature (−15 °C). X-ray diffraction analysis showed that the crystallinity index of TPOS decreased from 19.95% to 0.89%. Amorphous starch more easily combined with the plant fiber. Moreover, infrared spectrum analysis indicated that the OH stretching vibration peak of the TPOS/OUF composite moved to 3375.4 cm−1 from 3414.0 cm−1, which revealed that new hydrogen bonds were formed in the TPOS/OUF composite. The H atoms of the OH groups in starch and plant fiber were oxidized to highly polar H+. The N atoms in urea and O atoms in glycerol got quite close to these highly polar H+ groups and experienced an unusually strong field, which are known as hydrogen bonds. The newly formed hydrogen bonds made the plant fiber compatible with starch. Compatibility was experimentally validated by microscopic observation. For industrial application, new green composites and products were prepared using the TPOS/OUF composite slurry through a pollution-free process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Cleaner Production - Volume 185, 1 June 2018, Pages 357-365
نویسندگان
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