کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
8097589 1522072 2018 34 صفحه PDF سفارش دهید دانلود کنید
عنوان انگلیسی مقاله ISI
Diclofenac removal from water by adsorption using activated carbon in batch mode and fixed-bed column: Isotherms, thermodynamic study and breakthrough curves modeling
ترجمه فارسی عنوان
حذف دیکلوفناک از آب با جذب با استفاده از کربن فعال در حالت دسته ای و ستون ثابت: ایزوترم، مطالعه ترمودینامیکی و مدل سازی منحنی های دستیابی به موفقیت
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
چکیده انگلیسی
The presence of pharmaceutical compounds in the environment has been considered an emerging concern. Diclofenac has the highest acute toxicity among the non-steroidal anti-inflammatory drugs and it has been frequently detected in surface waters and wastewater treatment plants. Adsorption has been widely used to remove emerging contaminants such as pharmaceutical compounds from water sources and wastewaters. In this work, diclofenac adsorption was studied using activated carbon as adsorbent in batch process and fixed-bed column. Adsorption isotherms were determined through batch adsorption experiments, while fixed-bed adsorption was evaluated through a full factorial two-level experimental design involving three variables: initial pollutant concentration (20 - 100 mg L-1), weight of adsorbent (0.5 - 1.0 g) and volumetric feed flow rate (3 - 5 mL min−1). Adsorption equilibrium was investigated in different temperatures revealed that the Freundlich equation is suitable to describe the isotherms behavior in 298, 308 and 318 K. Thermodynamic analysis revealed negative ΔG0 and both positive ΔH0 and ΔS0, which indicated that diclofenac adsorption onto activated carbon is higher at higher temperatures and it is a spontaneous process. Breakthrough time, the time when 5% of initial concentration is detected in the effluent, was at higher initial concentration and lower flow rate. Fractional bed utilization increased with the increase of the initial concentration and flow rate, but decreased with higher amount of activated carbon. Breakthrough curves experimental data were fitted using Thomas, Bohart-Adams and Yan analytical models. Yan model showed the highest average of the determination coefficients (R² = 0.9842) of all experiments while the amounts adsorbed by the packed column were better predicted by Thomas equation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Cleaner Production - Volume 181, 20 April 2018, Pages 145-154
نویسندگان
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