کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8100767 1522114 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effects of waste fluid catalytic cracking on the properties of semi-hydrate phosphogypsum
ترجمه فارسی عنوان
اثر ترک خوردگی کاتالیزور مایع بر خواص نیمه هیدرات فسفو گپس
کلمات کلیدی
گچ نیمه هیدرات، فسفوگلیپس، زئولیت، ترک خوردگی کاتالیزوری مایع زباله،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
چکیده انگلیسی
Phosphogypsum poses environmental problems; therefore, this research paper examines and discusses the possibilities of effective utilization of phosphogypsum as a binding material. However, water-soluble primary calcium phosphate and fluoride, while remaining in phosphogypsum as unwanted impurities, makes it unsuitable for the production of gypsum-based products. This paper describes the process of adsorbing hazardous phosphogypsum impurities by zeolite. The waste fluid catalytic cracking (FCC) process catalyst based on synthetic zeolite Y was used in the experimental research described in this paper. In order to improve the properties of the binding material from phosphogypsum the ultrasound treatment of phosphogypsum paste was used. The samples were characterized by X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectrometer (EDS), the compressive strength of phosphogypsum specimens. The results showed, that the compressive strength increased about four times while using ultrasound treatment and waste FCC catalyst (zeolite Y) addition from 0.5 until 10% compared with specimens without zeolite and sonication. With the increase of zeolite by more than 10%, compressive strength decreased additionally. It was also determined that phosphogypsum paste used with waste FCC catalyst (zeolite Y), which was treated with ultrasound was an effective additive for neutralizing the acidic phosphogypsum medium. It neutralized the acidic admixtures, regulated the phosphogypsum hydration and the time setting duration as well. Additives modified the microstructure of hardened gypsum and increase its strength.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Cleaner Production - Volume 137, 20 November 2016, Pages 150-156
نویسندگان
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