کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8329200 | 1540209 | 2018 | 32 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Adsorption of Zn(II) ions by chitosan coated diatomaceous earth
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موضوعات مرتبط
علوم زیستی و بیوفناوری
بیوشیمی، ژنتیک و زیست شناسی مولکولی
زیست شیمی
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چکیده انگلیسی
In this work, chitosan coated diatomaceous earth (CCDE) beads were synthesized by a drop-wise method and characterized by FTIR, BET, SEM, EDS, and zeta potential for Zn(II) ion removal from aqueous solution in batch and continuous processes. Several parameters have been studied such as solution-pH, initial Zn(II) ion concentration, temperature, flow rate, and contact time to investigate the Zn(II) ion uptake. The maximum adsorption capacity of Zn(II) ion onto CCDE beads was 127.4Â mg/g in batch studies. The adsorption followed Pseudo second order and was well fitted to Langmuir model, indicating monolayer adsorption behavior. The continuous adsorption studies showed decreasing breakthrough and exhausted time with increasing flow rate of solution. The breakthrough points were 220 and 115Â min at flow rate 3 and 6Â mL/min, respectively. Loaded CCDE beads with Zn(II) ions were successfully regenerated by 0.2Â M NaOH without damaging the adsorbents and up to 87% recovery in the fourth cycle. Anions in the solution had an insignificant effect on Zn(II) ion uptake by CCDE beads. Overall results suggested that the prepared adsorbents could be employed as a low-cost, sustainable, and excellent alternative material for Zn(II) ion removal from wastewater.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Biological Macromolecules - Volume 106, January 2018, Pages 602-610
Journal: International Journal of Biological Macromolecules - Volume 106, January 2018, Pages 602-610
نویسندگان
Suhaib S. Salih, Tushar K. Ghosh,