کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8329525 | 1540212 | 2017 | 41 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Co-immobilization of Pd and Zn nanoparticles in chitosan/silica membranes for efficient, recyclable catalysts used in ullmann reaction
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کلمات کلیدی
موضوعات مرتبط
علوم زیستی و بیوفناوری
بیوشیمی، ژنتیک و زیست شناسی مولکولی
زیست شیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this study, an efficient heterogeneous catalyst including palladium (Pd) and zinc (Zn) nanoparticles supported on chitosan/silica (CS/SiO2) composite membrane is synthesized using partially etching of SiO2 technique. N2 sorption isotherm results shows that the prepared Pd-Zn@CS/SiO2 (1/1) porous membrane had a BET surface area of 26.50Â m2/g. High-resolution transmission electron microscopy (HR-TEM) and X-ray photoelectron spectroscopy (XPS), characterization of the catalyst shows that the Pd0 nanoparticles (below 5Â nm), and Zn0 aggregates (about 10-15Â nm) dispersed well in the CS/SiO2 matrix. Zinc crystal was also detected by X-ray diffraction study and HR-TEM observation. The prepared Pd-Zn@CS/SiO2 membrane catalyst is highly active for Ullmann reductive homocoupling reactions of aryl iodides and aryl bromides, and can be recycled 5 times without significant loss of activities. This work supplies a successful approach to realize Pd catalysts and Zn reducing reagent co-immobilized in the same carrier material with excellent catalytic performances.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Biological Macromolecules - Volume 105, Part 1, December 2017, Pages 575-583
Journal: International Journal of Biological Macromolecules - Volume 105, Part 1, December 2017, Pages 575-583
نویسندگان
Qi Liu, Mengdie Xu, Yudong Wang, Ruokun Feng, Zhen Yang, Shufeng Zuo, Chenze Qi, Minfeng Zeng,