Enhanced visible light photodegradation of pharmaceutical pollutant, warfarin by nano-sized SnTe, effect of supporting, catalyst dose, and scavengers

Improvement of new nanophotocatalysts enable to decompose the pharmaceutical pollutants with the aid of solar energy is of particular importance. In this research, the ability of SnTe photocatalyst for degradation of warfarin was enhanced and the separation difficulties of the used photocatalyst, from solutions was removed by immobilization of the photocatalyst on a suitable porous support. A novel nano-sized photocatalyst was prepared by coupling of SnTe on the surface of SBA-15 support. Characterization of the synthesized photocatalyst (SnTe@SBA-15) was performed by different methods including XRD, TEM, TGA, FT-IR, EDS and BET techniques. The map of constituent elements was also prepared. The results indicated that the activity of SnTe photocatalyst was significantly enhanced after immobilization on the support and lower catalyst dose was needed. The visible light irradiation was more effective than UV irradiation. The degradation process was kinetically fast, and the equilibrium was established within 10 min. Separation of the synthesized photocatalyst from the solution was much easier than the bulk SnTe. The regenerated photocatalyst retained more than 90% of its initial efficiency.