کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8862925 1620145 2018 41 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Artificial intelligence, regression model, and cost estimation for removal of chlorothalonil pesticide by activated carbon prepared from casuarina charcoal
موضوعات مرتبط
علوم زیستی و بیوفناوری علوم محیط زیست مهندسی محیط زیست
پیش نمایش صفحه اول مقاله
Artificial intelligence, regression model, and cost estimation for removal of chlorothalonil pesticide by activated carbon prepared from casuarina charcoal
چکیده انگلیسی
Chlorothalonil is a pesticide that can contaminate water bodies, detriment aquatic organisms, and cause cancers of the forestomach and kidney. In this study, a powdered activated carbon prepared from casuarina wood was used for the adsorption of chlorothalonil from aqueous solutions. Based on Scanning Electron microscopy and Fourier Transform Infrared Spectroscopy analyses, the adsorbent material comprised pores and multiple functional groups that favored the entrapment of chlorothalonil onto its surface. At initial chlorothalonil concentration of 480 mg L−1, the equilibrium uptake capacity was 187 mg g−1 at pH: 7, adsorbent dosage: 0.5 g L−1, contact time: 40 min, and room temperature (25 ± 4 °C). The kinetic and isotherm studies indicated that the rate constant of pseudo-second-order model (k2) was 0.003 g mg−1 min−1, and the monolayer adsorption capacity was 192 mg g−1. Results from a quadratic model demonstrated that the plot of adsorption capacity versus pH, chlorothalonil concentration, adsorbent dosage, and contact time caused quadratic-concave, linear-up, flat, and quadratic-linear concave up curves, respectively. An artificial neural network with a structure of 4-5-1 was able to predict the adsorption capacity (R2: 0.982), and the sensitivity analysis using connection weights showed that pH was the most influential factor. An economic estimation using amortization and operating costs revealed that an adsorption unit subjected to 100 m3 d−1 containing chlorothalonil concentration of 250 ± 50 mg L−1 could cost 1.18 $ m−3.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Sustainable Environment Research - Volume 28, Issue 3, May 2018, Pages 101-110
نویسندگان
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