Recurrent intrusive episodes in the Paleozoic metasedimentary upper crust during the Early Carboniferous time: The Veladero granitoid stock and the peraluminous andesite

The Veladero hill is a well-exposed upper crustal block located between the basement of Sierra de Umango (Western Sierras Pampeanas), and the Devonian - Carboniferous sedimentary sequence of Precordillera, at western Argentina. The hill is formed by schists, metaluminous granitoids and a subalkaline peraluminous andesite studied in this work. The country rocks are schists with mineralogy typically developed during a thermal event (e.g., cordierite, andalusite, biotite). The magmatic assemblage of the peraluminous andesite consists of K-feldspar + plagioclase + quartz + biotite + cordierite, with zircon, monazite, and oxides as accessory minerals. One representative sample from this rock was analyzed and has contents of SiO2 = 61%, Fe2O3t + MgO = 9.03, Na2O + K2O = 6.6%, and aluminium saturation index = 1.5, consistent with the mineralogy. A U-Pb zircon Concordia age of 347 ± 4 Ma was acquired by LA-MC-ICP-MS from zircon hosted in the peraluminous andesite, which together with an age of 342 ± 2 Ma recently published for the metaluminous Veladero granitoid stock, indicate that these two ages overlap within error. Combined mineral assemblage and Al-in-hornblende geobarometric data from the Veladero granitoid stock reveal that the granitic magma passed through ∼10 km of continental crust before reaching its final emplacement level. Field evidence indicates that the Veladero granitoid stock was emplaced under dominantly brittle deformation mechanisms and that the peraluminous andesite magma was generated and subsequently intruded into a previously emplaced magma mush close to solidification, making space by the displacement of large blocks of the host granite. Documented mingling relationships between granite and peraluminous andesite also support emplacement while the granite remained partially crystallized so that the time interval between the two was relatively short, probably on the scale of hundreds of thousands of years. We propose that the peraluminous magma was generated during the ascent of the metaluminous Veladero granitoid stock magma and that the most of the zircon crystallized in high middle crust from the Veladero granitoid stock. These zircons were subsequently recycled and incorporated in the peraluminous andesite. Zircons in the Veladero granitoid stock and the peraluminous andesite have indistinguishable morphology and support this interpretation. In situ Hf isotope data were obtained from igneous zircons in the peraluminous andesite and reveal a dominantly continental source (average εHf,t = −8.0, excluding one just positive value). εHf,t and TDM values from zircon in the Veladero granitoid stock and hosted in the peraluminous andesite are indistinguishable, which is consistent with their original crystallization in the Veladero granitoid stock. TDM values mainly range from 1.5 to 1.9 Ga (average = 1.7 Ga) and reveal a continental Gondwana signature. Consistently, detrital zircon ages from schists in which the igneous rocks were emplaced indicate Ordovician depositional ages and original Gondwanan provenance. However, based on previous studies a Devonian depositional age cannot be ruled out.