A general approach to advective-dispersive transport with multirate mass transfer

A numerical solution that is significantly more general than other semi-analytical solutions is presented for governing equations describing advective-dispersive transport with multirate mass transfer between mobile and immobile domains. The new solution approach is general in the sense that it does not impose any restrictive assumption on the spatial or temporal variability of advective and dispersive processes in the mobile domain. A single integro-differential equation (IDE) is developed for the concentration in the mobile domain by separating the concentration in the immobile domain from the set of two partial differential equations. The solution to the IDE requires the evaluation of a temporal integral of the concentration in the mobile domain, which is a function of the Laplace transform of the distribution of the mass transfer rate coefficient. The Laplace transform is not limited to flow fields with known constant velocities. The solutions for one- and two-dimensional examples obtained using the new approach agree with those obtained by existing semi-analytical and numerical approaches.