کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9566989 | 1503709 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Quantum modelling of photo-excited processes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
In the framework of quantum field theory and the dipole approximation, a self-consistent quantum molecular dynamics method is used to investigate the effect of chain length on the probability of formation or decay of both singlet and triplet excitons due to photon absorption or emission in isolated poly(p-phenylene vinylene) (PPV) chains. We found that the probability of the photo-induced intra-molecular singlet exciton formation and decay increases linearly with chain length and the probability for triplet exciton formation and decay does not depend on the chain length. Polymers with long chains have thus an advantage over small molecules in solar cell and light-emitting diode (LED) applications because their efficiency depends on the number of intra-molecular singlet excitons formed or emitted in the device, which is expected to increase with the conjugation length.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 248, Issues 1â4, 30 July 2005, Pages 450-454
Journal: Applied Surface Science - Volume 248, Issues 1â4, 30 July 2005, Pages 450-454
نویسندگان
Marta M.D. Ramos, Helena M.G. Correia,