کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9607927 | 46035 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Catalytically active and selective centers for production of É-caprolactam through liquid phase Beckmann rearrangement over H-USY catalyst
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Catalytically active and selective centers for production of É-caprolactam through liquid phase Beckmann rearrangement over H-USY catalyst Catalytically active and selective centers for production of É-caprolactam through liquid phase Beckmann rearrangement over H-USY catalyst](/preview/png/9607927.png)
چکیده انگلیسی
Heterogeneously catalyzed Beckmann rearrangement of cyclohexanone oxime to É-caprolactam over H-ultrastable Y (USY) zeolite, with the SiO2/Al2O3 ratio of 7, has been extensively studied under liquid-phase conditions using benzonitrile (PhCN) as solvent. Although the oxime conversion reached as high as 98%, a satisfactory selectivity to the lactam was not attained due to a rapid increase in the formation of cyclohexanone as a hydrolysis product. Direct addition of a small amount of water to the reaction mixture before heating retarded the hydrolysis of oxime reactant, resulting in a remarkable improvement in the lactam selectivity to 94%. It is believed that an energetically preferential adsorption of water on the oxime-hydrolysis sites and acid-catalyzed hydrolysis of PhCN are the important keys for a selective production of É-caprolactam. The FTIR spectroscopic studies on adsorbed PhCN have suggested that weak Brønsted acid sites are the active and selective sites for the Beckmann rearrangement, whereas the cyclohexanone formation is mainly catalyzed on Lewis acid sites.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 288, Issues 1â2, 15 July 2005, Pages 158-168
Journal: Applied Catalysis A: General - Volume 288, Issues 1â2, 15 July 2005, Pages 158-168
نویسندگان
Chawalit Ngamcharussrivichai, Peng Wu, Takashi Tatsumi,