کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9629086 | 461271 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The volatilization behavior of chlorine in coal during its pyrolysis and CO2-gasification in a fluidized bed reactor
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The volatilization behavior of chlorine in coal during its pyrolysis and CO2-gasification in a fluidized bed reactor The volatilization behavior of chlorine in coal during its pyrolysis and CO2-gasification in a fluidized bed reactor](/preview/png/9629086.png)
چکیده انگلیسی
The volatilization behavior of chlorine in three Chinese bituminous coals during pyrolysis and CO2-gasification in a fluidized bed reactor was investigated. The modes of occurrence of chlorine in raw coals and their char samples were determined using sequential chemical extraction method. The Cl volatility increases with increasing temperature. Below 600 °C the Cl volatility is different, depending on the coal type and the occurrence mode of Cl. Above 700 °C, the Cl volatilities for the three coals tested are all higher than 80%. About 41% of the chlorine in Lu-an coal and 73% of that in Yanzhou coal are organic forms, and most of them are covalently-bonded organic chlorine, which shows high volatile behavior even at low pyrolysis temperatures (below 500 °C), while the inorganic forms of chlorine in two coal samples are hardly volatilized even at low pyrolysis temperatures (below 400 °C). The restraining efficiency of addition of CaO on chlorine volatility is greatly dependent on pyrolysis temperature. The optimal restraining efficiency can be obtained at temperature range from 450 to 650 °C during pyrolysis of Lu-an coal. The volatile behavior of Cl is mainly dependent on temperature. Above 700 °C high volatility of Cl is obtained in both N2 and CO2 atmospheres.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 84, Issues 14â15, October 2005, Pages 1874-1878
Journal: Fuel - Volume 84, Issues 14â15, October 2005, Pages 1874-1878
نویسندگان
Wen Li, Hailiang Lu, Haokan Chen, Baoqing Li,