کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9629134 | 461265 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Absorption of HCl by limestone in hot flue gases. Part II: importance of calcium hydroxychloride
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Absorption of HCl by limestone in hot flue gases. Part II: importance of calcium hydroxychloride Absorption of HCl by limestone in hot flue gases. Part II: importance of calcium hydroxychloride](/preview/png/9629134.png)
چکیده انگلیسی
In the present study, the potential for products other than CaCl2 to be formed during HCl absorption was studied to shed light on the mechanisms of limestone chlorination. Experiments of different durations were made with a thermogravimetric apparatus, and the crystalline reaction products were identified by X-ray diffractometry (XRD). In the experiments, absorption products with Cl/Ca molar ratios of less than two were found to be formed in the early stages of absorbent chlorination. Calcium hydroxychloride, CaClOH, was found to be a particularly important chloride product; the XRD analyses of the chlorinated samples indicated that CaClOH is the first product to form when HCl is absorbed by limestone. The end product of chlorination, however, was found to be CaCl2. This result was true for the reactions of both calcined and uncalcined limestone at two temperature levels, 650 and 850 °C. The thermodynamic equilibrium calculations performed suggested that the CaClOH would not be thermodynamically stable above 700 °C for gas concentrations that are encountered in combustion installations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 84, Issues 12â13, September 2005, Pages 1674-1684
Journal: Fuel - Volume 84, Issues 12â13, September 2005, Pages 1674-1684
نویسندگان
Jatta Partanen, Peter Backman, Rainer Backman, Mikko Hupa,