کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9629177 | 461296 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Spectrophotometric study of molecular complex formation of asphaltene with two isomeric chloranils
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Coal derived asphaltene has been observed spectrophotometrically to form molecular complexes of charge transfer type with o- and p-chloranils. The CT absorption peaks have been detected by difference spectral method and the wavelengths of the CT peaks are in the expected order of electron affinities of the chloranils. The formation constants (K) have been determined using the Benesi-Hildebrand equation. The magnitudes of K are large compared to those of weak charge transfer complexes (for which Kâ101-103Â dm3Â molâ1) but are comparable to those of some recently reported supramolecular or inclusion complexes. The study reveals the presence of Ï-donor (i.e. aromatic) type of compounds in asphaltene molecule. It also supports the view that asphaltene molecules exist in solution forming micellar aggregate, in the cavities of which the chloranil molecules are included.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 84, Issues 2â3, JanuaryâFebruary 2005, Pages 153-157
Journal: Fuel - Volume 84, Issues 2â3, JanuaryâFebruary 2005, Pages 153-157
نویسندگان
A.K. Ghosh,