کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9674108 | 1453197 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hexavalent chromium removal by ferrochromium slag
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
The aim of this study is to demonstrate the potential of Cr(VI) generation during jigging operation applied for ferrochrome recovery from slag. The Cr(VI) concentrations of water contacted with ferrochromium slag (W/FS = 10) in a closed cycle after 50 batches were found as 0.61 mg/l. Also, reduction of Cr(VI) to Cr(III) and a subsequent precipitation of Cr(III) by using ferrochrome slag (FS) in a model solution has been aimed. The effects of amount of acid, contact time, FS dosage, initial Cr(VI) concentration and temperature on the Cr(VI) reduction have been studied through the batch runs. The amount of acid has been found to be the most effective parameter affecting the Cr(VI) reduction. A 10 g/l FS dosage and 3.5 ml/l H2SO4 (5 M) are sufficient to reduce all Cr(VI) in the model solution containing 10 mg/l Cr(VI) and for contact time of 60 min at 25 °C. In reduced solutions, precipitation of metal ions has been studied by using extra FS. A 60 g/l dosage of fresh FS can precipitate all Cr(III) and Fe ions in the reduced solution. Thus, it has been demonstrated that the treatment of jigging water stream to be generated in a ferrochrome plant containing Cr(VI) can be accomplished by using ferrochromium slag and sulphuric acid. Also, it has been determined that solid residues of the process are environmentally stable by applying TCLP test.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 126, Issues 1â3, 11 November 2005, Pages 176-182
Journal: Journal of Hazardous Materials - Volume 126, Issues 1â3, 11 November 2005, Pages 176-182
نویسندگان
Mehmet Erdem, H. Soner AltundoÄan, M. Deniz Turan, Fikret Tümen,