کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9674398 | 1453205 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A SEM and X-ray study for investigation of solidified/stabilized arsenic-iron hydroxide sludge
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: A SEM and X-ray study for investigation of solidified/stabilized arsenic-iron hydroxide sludge A SEM and X-ray study for investigation of solidified/stabilized arsenic-iron hydroxide sludge](/preview/png/9674398.png)
چکیده انگلیسی
Despite the fact that the solidification/stabilization of arsenic containing wastes with Portland cement and lime has an extensively documented history of use, the physical and chemical phenomena as a result of the interaction between arsenic and cement components have not been fully characterized. The study investigates the behavior of synthesized arsenic-iron hydroxide sludge, the by-product of arsenic removal by coagulation with ferric chloride, in solidified/stabilized matrices as well as its binding mechanisms by exploring the cementitious matrices in the micro-scale by scanning electron microscopy equipped with energy dispersive X-ray spectrometer (SEM-EDS). It was revealed that arsenic can be chemically fixed into cementitious environment of the solidified/stabilized matrices by three important immobilization mechanisms; sorption onto CSH surface, replacing SO42â of ettringite, and reaction with cement components to form calcium-arsenic compounds, the solubility limiting phases.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 118, Issues 1â3, 14 February 2005, Pages 185-195
Journal: Journal of Hazardous Materials - Volume 118, Issues 1â3, 14 February 2005, Pages 185-195
نویسندگان
Tanapon Phenrat, Taha F. Marhaba, Manaskorn Rachakornkij,