کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9681214 | 1455514 | 2005 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dissolved organic matter removal and disinfection byproduct formation control using ion exchange
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
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چکیده انگلیسی
Three different ion exchange resins were evaluated for their ability to remove dissolved organic matter (DOM) and reduce formation of disinfection byproducts (DBPs) formed during chlorination of surface waters sampled from the Intercoastal Waterway, Myrtle Beach, SC, USA (MB water), and the Tomhannock Reservoir, Troy, NY, USA (TMK water). At resin doses up to 600 mg/L, DOC levels were reduced from 30 to 70%, while total trihalomethane and haloacetic acid formation reactivity (i.e., TTHM/DOC and HAA9/DOC) was reduced from 40 to 70% and 50%, respectively. This suggests that ion exchange, alone or in combination with other processes, holds promise for removing a broad spectrum of DBP precursors. Chloride release was measured to confirm an ion exchange mechanism, but the possibility of physisorption and hydrogen bonding mechanisms was not ruled out. Ion exchange appeared to selectively remove high-specific UV-absorbing (i.e., SUVA254) DOM components from the TMK water; these components also had the highest molecular weights. However, this was not the case for the MB water. The “SUVA254 profile”, the relationship between SUVA254 and DBP formation reactivity (TTHM/DOC and HAA9/DOC), showed significant differences from the patterns observed previously for separation processes (e.g., coagulation and activated carbon adsorption) that rely primarily on hydrophobic interactions as a separation mechanism.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Desalination - Volume 176, Issues 1â3, 10 June 2005, Pages 189-200
Journal: Desalination - Volume 176, Issues 1â3, 10 June 2005, Pages 189-200
نویسندگان
Yongrui Tan, James E. Kilduff, Mehmet Kitis, Tanju Karanfil,