کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9693966 | 1459635 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermochemistry of adducts of some bivalent transition metal bromides with triphenylphosphine
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The compounds [MBrm(L)n] (where M is Mn(II), Fe(II), Co(II), Ni(II), Cu(I) or Zn(II); L = triphenyphosphine (tpp); m = 1 or 2; n = 1.5, 2 or 3) were synthesized and characterized by melting points, elemental analysis, thermal analysis and electronic and IR spectroscopy. The enthalpies of dissolution of the adducts, metal(II) bromides and triphenylphosphine in methanol or in a solution of 10% (v/v) triethanolamine, 40% (v/v) acetonitrile and 50% (v/v) methanol were measured and by using thermochemical cycles, the following thermochemical parameters for the adducts, have been determined: the standard enthalpies for the Lewis acid/base reaction (ÎrHθ), the standard enthalpies of formation (ÎfHθ), the standard enthalpies of decomposition (ÎDHθ), the lattice standard enthalpies (ÎMHθ) and the standard enthalpies of the Lewis acid/base reaction in the gaseous phase (ÎrHθ(g)). The mean bond dissociation enthalpies of the metal(II)-phosphorus bonds (D¯(MâP)) have been estimated.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 437, Issues 1â2, 15 October 2005, Pages 100-105
Journal: Thermochimica Acta - Volume 437, Issues 1â2, 15 October 2005, Pages 100-105
نویسندگان
Pedro Oliver Dunstan,