کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9694115 | 1459639 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of the magnetic field on the ferroelectric transition of KD2PO4 measured by a high resolution and super-sensitive differential scanning calorimeter
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The magnetic effect on the ferroelectric transition of single crystalline KD2PO4 (DKDP) was measured by using a high resolution and super-sensitive differential scanning calorimeter (DSC) working in a magnetic bore. The transition temperature of KD2PO4 with the magnetic field of 5 T along a-axis and along c-axis was 5.6 ± 0.8 and 2.8 ± 0.9 mK, respectively, higher than that without the magnetic field. The calculated temperature shifts of the transition due to the magnetic field along a-axis and along c-axis using the magneto-Clapeyron equation and the data of magnetic susceptibility were negative values, being contradictory to the experimental results. These results demand to consider another contribution in magnetic susceptibility. The high frequency term of magnetic susceptibility due to molecular motions was considered to play an important role in order to explain the positive experimental values.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 431, Issues 1â2, 15 June 2005, Pages 200-204
Journal: Thermochimica Acta - Volume 431, Issues 1â2, 15 June 2005, Pages 200-204
نویسندگان
Hideko Hayashi, Chieko Nonaka, Ken-ichi Tozaki, Hideaki Inaba, Chiaki Uyeda,