کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9694124 | 1459640 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Analysis of the nonisothermal crystallization kinetics in three linear aromatic polyester systems
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Analysis of the nonisothermal crystallization kinetics in three linear aromatic polyester systems Analysis of the nonisothermal crystallization kinetics in three linear aromatic polyester systems](/preview/png/9694124.png)
چکیده انگلیسی
Melt or cold crystallization kinetics has a strong bearing on morphology and the extent of crystallization, which significantly affects the physical properties of polymeric materials. Nonisothermal crystallization kinetics are often analyzed by the classical Johnson-Mehl-Avrami-Kolmogorov (JMAK) model or one of its variants, even though they are based on an isothermal assumption. As a result, during the nonisothermal (e.g. constant heating or cooling rate) crystallization of polymeric material, different sets of model parameters are required to describe crystallization at different rates, thereby increasing the total number of model parameters. In addition, due to the uncorrelated nature of these model parameters with the cooling or heating rate, accurate modeling at any intermediate condition is not possible. In the present work, these two limitations of the conventional approach have been eliminated by exhibiting the existence of a functional relationship between cooling or heating rate and effective activation energy during nonisothermal melt or cold crystallization in three linear aromatic polyesters. Furthermore, it has been shown that when the JMAK model is used in conjunction with this functional relationship, it is possible to precisely predict the experimental nonisothermal melt or cold crystallization kinetics at any linear cooling or heating rate with a single set of model parameters.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 430, Issues 1â2, June 2005, Pages 23-29
Journal: Thermochimica Acta - Volume 430, Issues 1â2, June 2005, Pages 23-29
نویسندگان
Satyam S. Sahay, Karthik Krishnan,