کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9694201 | 1459642 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Characterization of nanocrystalline anatase titania: an in situ HTXRD study
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
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چکیده انگلیسی
Nanocrystalline titania was synthesized by the hydrolysis of titanium iso-propoxide using ultrasonication. The powder XRD patterns of the sample were recorded in static air and vacuum using a Philips X-pert Pro diffractometer equipped with a high-temperature attachment (HTK16) from room temperature (298 K) to 1173 K and were analyzed by the Rietveld refinement technique. The anatase to rutile phase transformation was observed at 1173 K for the data collected in static air. Only 3% of anatase titania transformed to rutile when the experiments were carried out at 1173 K in vacuum. The phase transformation from anatase to rutile is accompanied by a continuous increase in the crystallite size of the anatase phase from 9 nm at room temperature to 28 nm at 873 K and then to 50 nm at 1173 K in air while the process of crystallite growth was suppressed in vacuum. A linear increase in the unit cell parameters 'a' and 'c', and thus, an overall linear increase in the unit cell volume was observed as a function of temperature in static air as well as vacuum. The lattice and volume thermal expansion coefficients (TEC), αa, αc and αV at 873 K are 8.57 à 10â6, 8.71 à 10â6 and 25.91 à 10â6 Kâ1 in air and 18.01 à 10â6, 14.95 à 10â6 and 51.13 à 10â6 Kâ1 in vacuum, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 427, Issues 1â2, March 2005, Pages 37-41
Journal: Thermochimica Acta - Volume 427, Issues 1â2, March 2005, Pages 37-41
نویسندگان
Neelam Jagtap, Mahesh Bhagwat, Preeti Awati, Veda Ramaswamy,