کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9694232 | 1459643 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A generalisation of the non-parametric, NPK (SVD) kinetic analysis method
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
جریان سیال و فرایندهای انتقال
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The non-parametric method of kinetic analysis using singular value decomposition of a matrix of data values, as proposed by Nomen and Sempere, is applied to differential and integral analysis of non-isothermal results. It is demonstrated again that a correction has to be applied to obtain the correct value of the pre-exponential constant A, as in Part 1 of this series. The two methods are tested using simulated data and show very accurate retrieval of the starting values of activation energy and pre-exponential constants. A set of data for the decomposition of calcite under vacuum, treated non-isothermally, was taken from the ICTAC study of kinetic methods. The results obtained agree reasonably with those reported from the study.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Thermochimica Acta - Volume 426, Issues 1â2, February 2005, Pages 23-31
Journal: Thermochimica Acta - Volume 426, Issues 1â2, February 2005, Pages 23-31
نویسندگان
G. Roger Heal,