کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
975481 | 933033 | 2007 | 15 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Direct and indirect correlations in low density supercritical Lennard-Jones fluids
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
ریاضیات
فیزیک ریاضی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We have carried out a detailed comparison of the direct and indirect correlation functions obtained from canonical molecular dynamics (NVT-MD) simulation of supercritical Lennard-Jones fluids to the results obtained by solving the Ornstein-Zernike equation with the approximate Duh-Henderson (DH) closure. The variations of equilibrium correlations are studied as functions of density at two supercritical isotherms near and away from the critical point. The direct and indirect correlations predicted using the DH closure provides a very good agreement with our simulation results at low densities. However, a marked deviation is observed at higher densities. These results are correlated to the discrepancies between the density and temperature dependence of the underlying bridge function. The implication of these results on the calculation of chemical potential and the Krichevskii parameter is also presented.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica A: Statistical Mechanics and its Applications - Volume 383, Issue 2, 15 September 2007, Pages 401-415
Journal: Physica A: Statistical Mechanics and its Applications - Volume 383, Issue 2, 15 September 2007, Pages 401-415
نویسندگان
Tapas R. Kunor, Srabani Taraphder,