کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
975482 933033 2007 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A hard sphere model of chemical reactions theory from the point of view of many-particle approach
موضوعات مرتبط
مهندسی و علوم پایه ریاضیات فیزیک ریاضی
پیش نمایش صفحه اول مقاله
A hard sphere model of chemical reactions theory from the point of view of many-particle approach
چکیده انگلیسی
On the basis of the previously obtained non-Markovian kinetic equation for irreversible chemical reaction A+B→C+B, we have examined a model of contact reaction between hard (impenetrable) spheres (singular force potential). The nature of the additional contribution to the rate constant is explained. As is found, for reactants with a hard core it is necessary to allow for the presence of initial correlations between them. A class of initial conditions for arbitrary form of the pair potential energy is established.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica A: Statistical Mechanics and its Applications - Volume 383, Issue 2, 15 September 2007, Pages 416-424
نویسندگان
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