کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
975482 | 933033 | 2007 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A hard sphere model of chemical reactions theory from the point of view of many-particle approach
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موضوعات مرتبط
مهندسی و علوم پایه
ریاضیات
فیزیک ریاضی
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چکیده انگلیسی
On the basis of the previously obtained non-Markovian kinetic equation for irreversible chemical reaction A+BâC+B, we have examined a model of contact reaction between hard (impenetrable) spheres (singular force potential). The nature of the additional contribution to the rate constant is explained. As is found, for reactants with a hard core it is necessary to allow for the presence of initial correlations between them. A class of initial conditions for arbitrary form of the pair potential energy is established.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica A: Statistical Mechanics and its Applications - Volume 383, Issue 2, 15 September 2007, Pages 416-424
Journal: Physica A: Statistical Mechanics and its Applications - Volume 383, Issue 2, 15 September 2007, Pages 416-424
نویسندگان
A.B. Doktorov, A.A. Kadetov, A.A. Kipriyanov,