کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9756936 | 1495289 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Raman frequency shifts of an internal mode near the tricritical and second order phase transitions in NH4Cl
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Raman frequency shifts of an internal mode near the tricritical and second order phase transitions in NH4Cl Raman frequency shifts of an internal mode near the tricritical and second order phase transitions in NH4Cl](/preview/png/9756936.png)
چکیده انگلیسی
This study gives our analysis for the frequency shifts of the v2 (1708 cmâ1) Raman mode in NH4Cl close to its tricritical (P = 1.6 kbar) and second order (P = 2.8 kbar) phase transitions. From our analysis, we extract the values of the critical exponent which describes the critical behavior of the Raman frequency shifts for this internal mode for the pressure conditions studied in NH4Cl. Our exponent value of α â 0.2 for the tricritical phase transition is close to the values of 1/16 (T < Tc) and 1/8 (T > Tc) for the specific heat, predicted from a 3D Ising model. Our exponent values for the second order phase transition (P = 2.8 kbar) for T < Tc and T > Tc are comparable with those reported in earlier studies.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 62, Issues 4â5, December 2005, Pages 926-930
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 62, Issues 4â5, December 2005, Pages 926-930
نویسندگان
H. Yurtseven, M.H. Tümkaya,