کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9757052 | 1495290 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Identification of static JT in copper(II) doped hexaimidazole M(II) lattices: MÂ =Â Co and Ni: An EPR study
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
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چکیده انگلیسی
Single crystal EPR studies on Cu(II) doped paramagnetic host lattices, hexaimidazole M(II) dichloride tetrahydrate (MÂ =Â Co and Ni), isomorphous with MÂ =Â Zn, have been carried out from room temperature to 77Â K to understand the nature of Jahn-Teller (JT) distortion in these paramagnetic host systems. The paramagnetic impurity, doped in the present two paramagnetic host lattices, shows anisotropic EPR spectra with superhyperfine from ligands, even at room temperature. An interesting observation noticed in the EPR spectra at room temperature is that there are more resonances corresponding to the second site in the paramagnetic hosts than in the diamagnetic host at 4.2Â K. This difference in behavior between the diamagnetic and paramagnetic host lattices indicates a change in the depth of the JT valleys. The spin Hamiltonian parameters are evaluated for Cu(II) ion in both the host lattices and the relaxation times have been calculated for the ion in cobalt host lattice only.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 62, Issues 1â3, November 2005, Pages 494-499
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 62, Issues 1â3, November 2005, Pages 494-499
نویسندگان
K. Velavan, R. Venkatesan, P. Sambasiva Rao,