کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
975725 | 933048 | 2007 | 18 صفحه PDF | دانلود رایگان |

In previous publications by the author the crystalline state was studied with the help of statistical methods based upon utilization of distribution functions. The approximation used for a crystal was not, however, fully adequate for fluids, which did not permit one, in particular, to construct a phase diagram with a triple and critical point. The present paper begins with analysis of the pair correlation function in crystals in order to find an approximation adequate for a crystal as well as fluid. The relevant thermodynamics is developed. It is shown that the fluid can be described, for example, by the hypernetted-chain equation or by the van der Waals or Dieterici equations of state, and such a description will be compatible with the proposed description of the crystal. A phase diagram is constructed which exhibits the region of the crystalline state together with the triple and critical points.
Journal: Physica A: Statistical Mechanics and its Applications - Volume 374, Issue 1, 15 January 2007, Pages 15–32