کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
975725 933048 2007 18 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Simultaneous statistical description of a crystal and fluid
موضوعات مرتبط
مهندسی و علوم پایه ریاضیات فیزیک ریاضی
پیش نمایش صفحه اول مقاله
Simultaneous statistical description of a crystal and fluid
چکیده انگلیسی

In previous publications by the author the crystalline state was studied with the help of statistical methods based upon utilization of distribution functions. The approximation used for a crystal was not, however, fully adequate for fluids, which did not permit one, in particular, to construct a phase diagram with a triple and critical point. The present paper begins with analysis of the pair correlation function in crystals in order to find an approximation adequate for a crystal as well as fluid. The relevant thermodynamics is developed. It is shown that the fluid can be described, for example, by the hypernetted-chain equation or by the van der Waals or Dieterici equations of state, and such a description will be compatible with the proposed description of the crystal. A phase diagram is constructed which exhibits the region of the crystalline state together with the triple and critical points.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica A: Statistical Mechanics and its Applications - Volume 374, Issue 1, 15 January 2007, Pages 15–32
نویسندگان
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