کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9760157 | 1498041 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Properties of zirconia thin layers elaborated by high voltage anodisation in view of SOFC application
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Properties of zirconia thin layers elaborated by high voltage anodisation in view of SOFC application Properties of zirconia thin layers elaborated by high voltage anodisation in view of SOFC application](/preview/png/9760157.png)
چکیده انگلیسی
In order to adapt the anodisation technique to SOFC application, zirconium and zirconium-niobium alloys were tested in various electrolytic media and applied potentials (up to 420 V). The elaborated ZrO2 insulating layers were characterised in situ by electrochemical impedance spectroscopy and their thicknesses were determined as ranging up to 1 μm. The effect of thermal annealing treatment of layers prepared in various experimental conditions was investigated by X-ray diffraction (XRD) and solid-state electrochemical impedance spectroscopy in a planar configuration. The effect of the growing conditions on significant parameters such as zirconia crystallite size, zirconia conductivity and activation energy were deduced up to 800 °C. The possibility of using the anodisation process for fuel cell devices is discussed. This study demonstrates that it surely requires the use of more efficient dopants, such as yttria.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 151, 10 October 2005, Pages 85-92
Journal: Journal of Power Sources - Volume 151, 10 October 2005, Pages 85-92
نویسندگان
Xabier Montero, Thierry Pauporté, Armelle Ringuedé, Rose-Noelle Vannier, Michel Cassir,