کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9760303 1498046 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Improvement on cycling efficiency of lithium by PEO-based surfactants in cross-linked gel polymer electrolyte
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Improvement on cycling efficiency of lithium by PEO-based surfactants in cross-linked gel polymer electrolyte
چکیده انگلیسی
The effect of poly(ethylene oxide) (PEO)-based surfactant in the gel polymer electrolyte on the cycling efficiency of lithium was investigated by means chronopotentiometry. The gel polymer electrolyte was prepared by thermal curing using bisphenol A ethoxylate diacrylate as a cross-linker. While an improvement in cycling efficiency of lithium was found for the electrolytes containing both of perfluorinated and star-shaped PEO-based surfactants, the better cycling efficiency was observed for the star-shaped surfactants than that for the perfluorinated surfactant. More than 90% of cycling efficiency of lithium was achieved for the polymer electrolyte using star-shaped PEO surfactants. The cycling efficiency of lithium in the gel polymer electrolyte containing star-shaped surfactant increased as increasing of the molecular weight of side chain. By using star-shaped PEO surfactant, the interface resistance was almost constant during the repeated cycles. The star-shaped PEO-based surfactants seem to be very effective to form stable SEI layer.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 146, Issues 1–2, 26 August 2005, Pages 171-175
نویسندگان
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