کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9760310 | 1498046 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical properties of nano-sized Li4Ti5O12 powders synthesized by a sol-gel process and characterized by X-ray absorption spectroscopy
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Nano-sized spinel Li4Ti5O12 powders were synthesized by a sol-gel process. The cubic spinel structure without impurity phase of the synthesized Li4Ti5O12 powders was confirmed by X-ray diffraction. The average grain size of the synthesized powders was found to be around 39 nm. In situ X-ray absorption spectroscopy (XAS) has been performed on the Li4Ti5O12 electrode to investigate its change in the oxidation state and the local environment of the electrode during charging and discharging processes. The X-ray absorption near edge spectroscopy (XANES) analysis showed that the absorption edge energy shifts towards lower and higher energy, respectively, during discharge and charge processes, indicating the reversibility of the electrode is quite good. It was worthy to note that the discharging capacity and the charging capacity obtained for the nano-sized Li4Ti5O12 electrode in the potential range of 0.01-1.75 V are 255 and 242 mAh gâ1, respectively. However, the specific charge capacity obtained in the potential range of 1.0-2.0 V is 126 mAh gâ1. The spinel Li4Ti5O12 electrode maintains the cubic spinel structure for repeated cycling resulting in good cyclability and the capacity retention.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 146, Issues 1â2, 26 August 2005, Pages 204-208
Journal: Journal of Power Sources - Volume 146, Issues 1â2, 26 August 2005, Pages 204-208
نویسندگان
M. Venkateswarlu, C.H. Chen, J.S. Do, C.W. Lin, T.C. Chou, B.J. Hwang,