Quantum theory of irreversibility

A generalization of the Gibbs–von Neumann entropy is proposed based on the quantum BBGKY (Bogolyubov–Born–Green–Kirkwood–Yvon) hierarchy as the non-equilibrium entropy for an NN-body system. By using a generalization of the Liouville–von Neumann equation describing the evolution of a density superoperator, the entropy production for an isolated system is calculated, being non-zero in general. The existence of a non-zero entropy production allows us, following the procedure of non-equilibrium thermodynamics to introduce a master matrix for which a microscopic expression is obtained. After this, as a test of our theory the quantum Boltzmann equation is derived in terms of a transition superoperator related to this master matrix.