کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
977203 | 933178 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Polydisperse chains placed on a one-dimensional lattice
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موضوعات مرتبط
مهندسی و علوم پایه
ریاضیات
فیزیک ریاضی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Using a transfer matrix technique, we calculate the entropy of polydisperse chains placed on an one-dimensional lattice, as a function of the density of internal and endpoint monomers. The polydispersivity is determined considering different activities for the two types of monomers, as is usual for equilibrium polymerization and living polymers. If the mean number of monomers in the chains is fixed, the entropy as a function of the density of monomers displays a maximum and is limited from below by the entropy of monodisperse chains. The increase of entropy due to the polydispersivity is a linear function of the density of monomers. We also calculate the distribution of chain sizes, obtaining an exponential relation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica A: Statistical Mechanics and its Applications - Volume 368, Issue 2, 15 August 2006, Pages 442-448
Journal: Physica A: Statistical Mechanics and its Applications - Volume 368, Issue 2, 15 August 2006, Pages 442-448
نویسندگان
Jürgen F. Stilck, Minos A. Neto, Wellington Gomes Dantas,