کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
977569 1480145 2015 16 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
On the stochastic thermodynamics of reactive systems
ترجمه فارسی عنوان
در ترمودینامیک تصادفی سیستم های واکنشی
کلمات کلیدی
ترمودینامیک تصادفی، معادله استاد سیستم های واکنش پذیر، قضیه نوسان
موضوعات مرتبط
مهندسی و علوم پایه ریاضیات فیزیک ریاضی
چکیده انگلیسی


• We develop a framework for the stochastic thermodynamics of reactive systems.
• We derive constraints acting on the transition probabilities of reactive events.
• The constraints make the stochastic picture coherent with classical thermodynamics.
• They affect the properties of stochastic fluxes, forces and entropy production.
• We show how they can be used to derive various types of fluctuation theorems.

We develop a theoretical framework for the stochastic thermodynamics of reactive systems. We show that the transition probabilities per unit time of reactive events must satisfy specific constraints, in order for stochastic approaches to lead to physically meaningful results in the macroscopic limit. We discuss how these constraints affect the properties of stochastic fluxes and forces, and entropy production. We also see how they can be used to derive various expressions of fluctuation theorems.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica A: Statistical Mechanics and its Applications - Volume 428, 15 June 2015, Pages 178–193
نویسندگان
,