کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9808659 | 1517354 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of PEG-grafted silica particles using emulsion method
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Low-molecular-weight poly(ethylene glycol) (PEG) was grafted onto the surface of silica particles by a two-step addition process. To prepare PEG-grafted silica particles, PEGME-IPTES monomers were synthesized by the reaction of 3-(triethoxysilyl)propyl isocyanate (IPTES) with poly(ethylene glycol) methyl ether (PEGME) in the presence of dibutyltin dilaurate. To remove PEGME residues, excessive IPTES was added to the solution. The peak for a urethane carbonyl group of PEGME-IPTES was observed at 1722 cmâ1 by FT-IR spectroscopy. Through the sequential addition of TEOS and PEGME-IPTES monomers, PEG was introduced onto the surface of silica particles. The introduction of PEG onto the surface was observed by SEM, Brunauer-Emmett-Teller (BET), and FT-IR spectroscopy. When PEG was grafted onto the surface of silica particles, the surface area of silica particles decreased and the average pore diameter increased. The peak for urethane carbonyl group and alkyl group of PEG appeared at 1722 cmâ1 and 2920 cmâ1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 59, Issues 8â9, April 2005, Pages 929-933
Journal: Materials Letters - Volume 59, Issues 8â9, April 2005, Pages 929-933
نویسندگان
Chul Oh, Chang Do Ki, Ji Young Chang, Seong-Geun Oh,