کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9818114 | 1518776 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mass spectrometric and theoretical studies on the fragmentation mechanisms of hexamethyldigermane and hexamethyldisilane ions in the gas phase
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سطوح، پوششها و فیلمها
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Mass spectrometric and theoretical studies on the fragmentation mechanisms of hexamethyldigermane and hexamethyldisilane ions in the gas phase Mass spectrometric and theoretical studies on the fragmentation mechanisms of hexamethyldigermane and hexamethyldisilane ions in the gas phase](/preview/png/9818114.png)
چکیده انگلیسی
Fragmentation mechanisms of hexamethyldigermane and hexamethyldisilane ions have been investigated using the collision-induced dissociation-mass spectrometry/mass spectrometry (CID-MS/MS) and ab initio MO calculations. The results of CID-MS/MS spectra showed that the [(CH3)3GeGe(CH3)3]+ ion was fragmented to be (CH3)3Ge+, followed by the secondary fragmentation generating CH3Ge+. The results of ab initio calculations showed that a C2H4 elimination occurred more easily than a C2H6 elimination from (CH3)3Ge+ in the low energy region.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms - Volume 232, Issues 1â4, May 2005, Pages 217-222
Journal: Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms - Volume 232, Issues 1â4, May 2005, Pages 217-222
نویسندگان
Takae Takeuchi, Yuko Shirai, Takaomi Matsutani, Masato Kiuchi,