Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; PhIO, iodosylbenzene; PhINTs, (tosylimino)iodobenzene; IBX, 2-iodoxybenzoic acid; EXAFS, extended X-ray absorption fine structure; NMR, nuclear magnetic resonance; porph, porphyrin; TDCPP, tetra-(2,6-Cl2C6H3)porphyrin; TPP, tetraphenylporphyrin; ESI-MS, e
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XAS study of iron speciation in soils and waters from a boreal catchment
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; CN, coordination number; DOC, dissolved organic carbon; EXAFS, extended X-ray absorption fine structure; LCF, linear combination fitting; MS, multiple scattering; NOM, natural organic matter; TOC, total organic carbon; WT, wavelet transform; XANES, X-ray
Monitoring excited state dynamics in cis-[Ru(bpy)2(py)2]2+ by ultrafast synchrotron techniques
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; APS, Advanced photon source; DFT, Density functional theory; DW, Debye–Waller; ES, Excited state; ESRF, European synchrotron radiation facility; EXAFS, Extended X-ray absorption fine structure; GS, Ground state; MC, Metal centred (excited state); MLCT, Me
Hydrothermal synthesis and solid-state structure of Tc2(μ-O2CCH3)4Cl2
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; SC-XRD, single crystal X-ray diffraction; EXAFS, extended X-ray absorption fine structure; FTIR, Fourier transform infrared spectroscopy; DWF, Debye–Waller factorTechnetium; Potassium pertechnetate; Carboxylate-bridged dimers; Quadruple metal–metal bonds;
Systematic analysis of palladium–graphene nanocomposites and their catalytic applications in Sonogashira reaction
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; Pd/G, Pd–graphene; GO, graphene oxide; XRD, X-ray diffraction; FT-IR, Fourier transform infrared spectroscopy; XPS, X-ray photoelectron spectroscopy; XANES, X-ray absorption near edge structure; EXAFS, extended X-ray absorption fine structure; TEM, transm
Ribonucleotide reductase class I with different radical generating clusters
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; CD, circular dichroism; dNDP, deoxyribonucleotidediphosphates; dNTP, deoxyribonucleotidetriphosphates; EBV, Epstein Barr virus; EPR, electron paramagnetic resonance; ENDOR, electron-nuclear double resonance; EXAFS, extended X-ray absorption fine structure
Enhanced electrocatalytic performance due to anomalous compressive strain and superior electron retention properties of highly porous Pt nanoparticles
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; HP-Pt, highly porous Pt; TTAB, tetradecyl trimethylammonium bromide; ORR, oxygen reduction reaction; PEMEC, proton exchange membrane fuel cell; HRPD, high-resolution powder diffraction; EXAFS, extended X-ray absorption fine structure; XANES, X-ray absorpt
Atomic structure of cobalt-oxide nanoparticles active in light-driven catalysis of water oxidation
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; Artificial photosynthesis; Photocatalysis; Solar fuels; Water oxidation; X-ray absorption spectroscopyCoCat, electrodeposited Co oxide catalyst for water oxidation; EXAFS, extended X-ray absorption fine structure; FT, Fourier transformation; M2P, methylen
High-valent [MnFe] and [FeFe] cofactors in ribonucleotide reductases
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; BVS, bond-valence-sum; Ct, Chlamydia trachomatis; DFT, density functional theory; DTT, dithiothreitol; EPR, electron paramagnetic resonance spectroscopy; EXAFS, extended X-ray absorption fine structure; FWHM, full width at half maximum; Mm, Mus musculus (
Structural and mechanistic investigations of photosystem II through computational methods
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; Chl, chlorophyll; DFT, density functional theory; EPR, electron paramagnetic resonance; ESEEM, electron spin echo envelope modulation; ESP, electrostatic potential; EXAFS, extended X-ray absorption fine structure; FT-IR, Fourier transform infra-red; HF, H
X-ray absorption fine structure of artificial antigens for cadmium
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; BSA, bovine serum albumin; OVA, ovalbumin; p-SCN-Bn-DTPA, 2-(4-isothiocyanatobenzyl)-diethylenetriaminepentaacetic acid; XAFS, X-ray absorption fine structure; EXAFS, extended X-ray absorption fine structure; XANES, X-ray absorption near edge structure; S
The impact of EDTA on lead distribution and speciation in the accumulator Sedum alfredii by synchrotron X-ray investigation
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; EDTA; Lead; Localization; Sedum alfredii; Speciation; X-ray absorption spectroscopyAE, Accumulating ecotype; EXAFS, Extended X-ray absorption fine structure; NAE, Non-accumulating ecotype; XAS, X-ray absorption spectroscopy
Biosynthesis of nitrogenase FeMoco
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; Fe protein, iron protein; MoFe protein, molybdenum–iron protein; FeMoco, iron–molybdenum cofactor; XAS, X-ray absorption spectroscopy; EXAFS, extended X-ray absorption fine structure; EPR, electron paramagnetic resonanceNitrogen fixation; Nitrogenase; FeM
Crystal Structures of Cobalamin-Independent Methionine Synthase (MetE) from Streptococcus mutans: A Dynamic Zinc-Inversion Model
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; EXAFS, extended X-ray absorption fine structure; PDB, Protein Data BankMetE; dynamic equilibrium; methionine synthase; homocysteine; methyltetrahydrofolate
Bioinorganic chemistry of molybdenum and tungsten enzymes: A structural–functional modeling approach
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; dithiolene, dithiolene in its dithiolate form unless otherwise noted; mnt, maleonitrile dithiolate; bdt, 1,2-benzene dithiolate; OAT, oxygen atom transfer; EXAFS, extended X-ray absorption fine structure; FMO, frontier molecular orbital; SO, sulfite oxida
The history of the discovery of the molybdenum cofactor and novel aspects of its biosynthesis in bacteria
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; cPMP, cyclic pyranopterin monophosphate; EDAX, energy dispersive analysis of X-rays; EXAFS, extended X-ray absorption fine structure; MCD, molybdopterin cytosine dinucleotide cofactor; MGD, molybdopterin guanine dinucleotide cofactor; Moco, molybdenum cof
Comparative molecular chemistry of molybdenum and tungsten and its relation to hydroxylase and oxotransferase enzymes
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; Ad, adamantyl; BDE, bond dissociation energy; DMSOR, dimethylsulfoxide reductase; edta, ethylenediaminetetraacetate(4−); eu, cal deg−1 mol−1; EXAFS, extended X-ray absorption fine structure; FMDH, N-formylmethanofuran dehydrogenase; FMO, frontier molecula
Structure and catalytic mechanism of the β-carbonic anhydrases
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; CA, carbonic anhydrase; EXAFS, extended X-ray absorption fine structure; Rubisco, ribulose-1,5-bisphoshate carboxylase; HICA, Haemophilus influenzae β-CA; ECCA, Escherichia coli β-CA; MTCA, Methanobacterium thermoautotrophicum β-CA; PPCA, Porphyridium pur
The Structure of Sedoheptulose-7-Phosphate Isomerase from Burkholderia pseudomallei Reveals a Zinc Binding Site at the Heart of the Active Site
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; CPS, capsular polysaccharide; CPS-I, type I capsular polysaccharide; dHep, l-glycero-α-d-manno-heptopyranose; EXAFS, extended X-ray absorption fine structure; LPS, lipopolysaccharide; M7P, d-glycero-d-manno-heptopyranose-7-phosphate; PDB, Protein Data Ban
The crystal structure of C176A mutated [Fe]-hydrogenase suggests an acyl-iron ligation in the active site iron complex
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; methenyl-H4MPT+, methenyl-tetrahydromethanopterin; methylene-H4MPT, methylene-tetrahydromethanopterin; FeGP, iron–guanylylpyridinol; EXAFS, extended X-ray absorption fine structure; ATR-IR, attenuated total reflection infrared; DTT, dithiothreitol; r.m.s.
Selenium adsorption to aluminum-based water treatment residuals
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; EXAFS, extended X-ray absorption fine structure; ICP-AES, inductively coupled plasma-atomic emission spectroscopy; WTR, aluminum-based water treatment residuals; XAS, X-ray absorption spectroscopy; XAFS, X-ray absorption fine structure; XRD, X-ray diffrac
Calcium Exchange and Structural Changes during the Photosynthetic Oxygen Evolving Cycle
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; PSII, photosystem II; chl, chlorophyll; DCBQ, 2,6-dichloro-1,4-benzoquinone; EPR, electron paramagnetic resonance; ESEEM, electron spin echo envelope modulation; EXAFS, extended x-ray absorption fine structure; FT-IR, Fourier transform infrared; OEC, oxyg
The calcium and chloride requirements of the O2 evolving complex
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; EDTA, ethylenediaminetetraacetic acid; EGTA, ethylene glycol bis(2-aminoethyl ether)-N,N,N′,N′-tetraacetic acid; EPR, electron paramagnetic resonance; ESEEM, electron spin echo envelope modulation; EXAFS, extended X-ray absorption fine structure; FTIR, Fo
Structural Insights into the Design of Inhibitors for the L1 Metallo-β-lactamase from Stenotrophomonas maltophilia
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; MBL, metallo-β-lactamase; PDB, Protein Data Bank; rmsd, root-mean-square deviation; EXAFS, extended X-ray absorption fine structure; D-cap, 1-(2S)-3-mercapto-2-methyl-propionyl-d-proline; MP2, N-[(benzyloxy) carbonyl]-l-cysteinyl glycineLactamase; metallo
Access channels and methanol binding site to the CaMn4 cluster in Photosystem II based on solvent accessibility simulations, with implications for substrate water access
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; PSII, Photosystem II; P680, the primary donor in PSII; YZ, tyrosine 161 of the PSII D1 polypeptide; EPR, electron paramagnetic resonance; ESEEM, electron spin echo envelope modulation; CW, continuous wave; EXAFS, extended X-ray absorption fine structure;
Photoassembly of the water-oxidizing complex in photosystem II
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; CCCP, carbonyl cyanide m-chlorophenylhydrazone; CW, continuous wave; EPR, electron paramagnetic resonance; EDTA, ethylenediaminetetraacetic acid; ESEEM, electron spin echo envelop modulation spectroscopy; EXAFS, extended X-ray absorption fine structure; M
Protein ligation of the photosynthetic oxygen-evolving center
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; Chl, chlorophyll; DCMU, 3-(3,4-dichlorophenyl)-1,1-dimethylurea; EPR, electron paramagnetic resonance; ENDOR, electron nuclear double resonance; EXAFS, extended X-ray absorption fine structure; FTIR, Fourier transform infrared; P680, chlorophyll species t
Reflections on small molecule manganese models that seek to mimic photosynthetic water oxidation chemistry
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; OEC, oxygen evolving complex; PSII, photosystem II; XRD, X-ray diffraction; XAS, X-ray absorption spectroscopy; XANES, X-ray absorption near-edge spectroscopy; EXAFS, extended X-ray absorption fine structure; sal, salicylicate; bipy, 2,2′-bipyridine; zfs,
The prokaryotic complex iron–sulfur molybdoenzyme family
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; CISM, complex iron–sulfur molybdoenzyme; DmsABC, E. coli DMSO reductase; DorA, soluble Rhodobacter DMSO reductase; Em, midpoint potential; EPR, electron paramagnetic resonance; ETR, electron transfer relay; EXAFS, extended X-ray absorption fine structure;
Immobilization of organorhenium(VII) oxides
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; Acac, acetylacetonate; bpy, 2,2′-bipyridyl; Cp, cyclopentadiene; dppa, bis(diphenylphosphino)amine; Et, ethyl; EXAFS, extended X-ray absorption fine structure; IR, infra red; MCM, mobile crystalline material; Me, methyl; MTO, methyltrioxorhenium; NMR, nuc
From the Periplasmic Signaling Domain to the Extracellular Face of an Outer Membrane Signal Transducer of Pseudomonas aeruginosa: Crystal Structure of the Ferric Pyoverdine Outer Membrane Receptor
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; TBDR, TonB-dependent receptor; Pvd, pyoverdine; Ga, gallium; EXAFS, extended X-ray absorption fine structure; XAS, X-ray absorption spectroscopymembrane proteins; signal transduction; TonB-dependent receptors; ferric pyoverdine; FpvA
Purification, crystallization and X-ray diffraction analyses of the T. elongatus PSII core dimer with strontium replacing calcium in the oxygen-evolving complex
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; PSI and II, photosystem I and II; OEC, oxygen-evolving complex; PQ, plastoquinone; Chl, chlorophyll; EPR, electron paramagnetic resonance; ICP, inductively coupled plasma optical emission spectrometry; EXAFS, extended X-ray absorption fine structure; FT-I
Characterization of the metallocenter of rabbit skeletal muscle AMP deaminase. A new model for substrate interactions at a dinuclear cocatalytic Zn site
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; AMPD, AMP deaminase; ADA, adenosine deaminase; HPRG, histidine-proline-rich-glycoprotein; PRN, purine ribonucleoside; EXAFS, Extended X-ray Absorption Fine Structure; FT, Fourier Transform; TNBS, trinitrobenzene sulfonic acid; XANES, X-ray Absorption Near
Characterization of the metallocenter of rabbit skeletal muscle AMP deaminase. Evidence for a dinuclear zinc site
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; AMPD, AMP deaminase; HPRG, histidine-proline-rich-glycoprotein; XAS, X-ray absorption spectroscopy; EXAFS, Extended X-ray Absorption Fine Structure; FT, Fourier Transforms; BVS, bond valence sum; CD, Circular Dichroism; SOD1, superoxide dismutaseAMP deami
Structural Studies of the Alzheimer’s Amyloid Precursor Protein Copper-binding Domain Reveal How it Binds Copper Ions
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; APP, Amyloid precursor protein; APS, Advanced Photon Source; BACE, β-site APP cleaving enzyme; CuBD, copper binding domain of APP; EPR, electron paramagnetic resonance; EXAFS, extended X-ray absorption fine structure; GFD, growth factor domain of APP; r.m
Detecting transient protein–protein interactions by X-ray absorption spectroscopy: The cytochrome c6-photosystem I complex
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; (Cc6), Cytochrome c6; EXAFS, extended X-ray absorption fine structure; FT, Fourier transform; PSI, photosystem I; PSIHg, Hg-containing photosystem I; XANES, X-ray absorption near edge structure; XAS, X-ray absorption spectroscopy; XRD, X-ray diffractionCy
Transient binding of plastocyanin to its physiological redox partners modifies the copper site geometry
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; Cf, water-soluble fragment of cytochrome f; ET, electron transfer; EXAFS, extended x-ray absorption fine structure; FT, Fourier transform; HOMO, highest occupied molecular orbital; NIR, nitrite reductase; Pc, plastocyanin; PSI, photosystem I; PSIHg, Hg-co
Bridging-type changes facilitate successive oxidation steps at about 1 V in two binuclear manganese complexes—implications for photosynthetic water-oxidation
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; bpy, 2,2-bipyridine; EPR, electron paramagnetic resonance; EXAFS, extended X-ray absorption fine structure; PSII, photosystem II; SCE, saturated calomel electrode; TyrZ, specific tyrosine residue of PS II; XANES, X-ray absorption near-edge structure; XAS,
Gold Nanocluster Formation using Metallothionein: Mass Spectrometry and Electron Microscopy
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; metallothionein; mass spectrometry; transmission electron microscopy; nanocluster; gold tagTEM, transmission electron microscopy; MT, metallothionein; EXAFS, extended X-ray absorption fine structure; ESI, electrospray ionization; MS, mass spectrometry; MA
Iron Incorporation in Streptococcus suis Dps-like Peroxide Resistance Protein Dpr Requires Mobility in the Ferroxidase Center and Leads to the Formation of a Ferrihydrite-like Core
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; DW, Debye-Waller; Dps, DNA-binding protein from starved cells; Dpr, Dps-like peroxide resistance protein; EXAFS, extended X-ray absorption fine structure; ICP-MS, inductively coupled plasma mass spectroscopy; XAS, X-ray absorption spectroscopyoxidative st
The structure of the Ni–Fe site in the isolated HoxC subunit of the hydrogen-sensing hydrogenase from Ralstonia eutropha
Keywords: EXAFS، ساختار ریز جذب جذب اشعه ایکس; AAS, atomic absorption spectroscopy; DCIP, 2,6-dichlorophenolindophenol; EPR, electron paramagnetic resonance spectroscopy; EXAFS, extended X-ray absorption fine structure; IR, infrared spectroscopy; HoxC, large subunit of the RH; HoxCST, Strep-tag isolat