Keywords: انتقال هیدریدها; Tetrahydroborate; Borohydride; Thermodynamic hydridicity; Hydride transfer;
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Keywords: انتقال هیدریدها; Ozone; 2-Propanol; Hydride transfer; Rate constant; Pre-exponential factor; Activation energy;
Keywords: انتقال هیدریدها; Asymmetric catalysis; Ruthenium; Hydride transfer; Multi-substrate screening; Aliphatic ketones;
Keywords: انتقال هیدریدها; Alkene oligomerization; Hydride transfer; Alkylation; Zeolites; Confinement; Acid strength; Heteropolyacids;
Keywords: انتقال هیدریدها; Cellulose hydrolysis; Solid acid catalysts; Lewis acidity; Tungstated zirconia; Hydride transfer; 2,5-Hexanedione;
Keywords: انتقال هیدریدها; Alkanal; Deoxygenation; Brønsted acid site; Zeolite; Transfer hydrogenation; Hydride transfer; Hydride ion affinity
Synthesis and evaluation of hemisalen type ligands based on chiral diamine and their use with ruthenium (II) as water-soluble catalysts for the ATH of aromatic ketones
Keywords: انتقال هیدریدها; Asymmetric catalysis; Hydride transfer; Ruthenium; Hemisalen ligands; Chiral pool;
Sanguinarine is reduced by NADH through a covalent adduct
Keywords: انتقال هیدریدها; Benzophenanthridine alkaloids; Ene adduct; Hydride transfer; LC-MS; NADH; NADH depletion; Redox cycling; Sanguinarine;
Substitutions of a buried glutamate residue hinder the conformational change in horse liver alcohol dehydrogenase and yield a surprising complex with endogenous 3â²-Dephosphocoenzyme A
Keywords: انتقال هیدریدها; Enzyme kinetics; Coenzyme binding; Conformational change; Hydride transfer; X-ray crystallography; Protein structure; ADH; alcohol dehydrogenase; E267H; substitution Glu-267 with histidine residue; E267â¯H/N; substitution with either histidine or asparag
Collision-induced dissociation of protonated cyproheptadine: Ion-neutral complex mediated electron transfer versus hydride transfer reaction
Keywords: انتقال هیدریدها; Cyproheptadine; Electrospray ionization mass spectrometry; Hydride transfer; Electron transfer; Ion/neutral complex;
Catalytic hydrodehalogenation over supported gold: Electron transfer versus hydride transfer
Keywords: انتقال هیدریدها; Selective hydrodehalogenation; Photocatalysis; Supported gold; Electron transfer; Hydride transfer;
NHC-induced conversion of a W-Ge double bond into the triple bond through formation of W-Ge single and double bonded intermediates
Keywords: انتقال هیدریدها; Germylene complex; Germylyne complex; NHC-carbene; Proton transfer; Hydride transfer; X-ray diffraction;
Substitutions of S101 decrease proton and hydride transfers in the oxidation of betaine aldehyde by choline oxidase
Keywords: انتقال هیدریدها; Choline oxidase; Reductive half-reaction; Aldehyde oxidation; Hydrophobicity; Hydride transfer; FAD;
Promotion on light olefins production through modulating the reaction pathways for n-pentane catalytic cracking over ZSM-5 based catalysts
Keywords: انتقال هیدریدها; n-Pentane; Light olefins; Protolytic cracking; Hydride transfer; Dehydrogenation cracking; Redox cracking;
Direct conversion of carboxylic acids (Cn) to alkenes (C2n − 1) over titanium oxide in absence of noble metals
Keywords: انتقال هیدریدها; Aldol condensation; Carboncarbon bond formation; Ketonic decarboxylation; Hydride transfer; Second generation diesel fuel
A comparative theoretical study of the hydride transfer mechanisms during LiAlH4 and LiBH4 reductions
Keywords: انتقال هیدریدها; Hydride transfer; LiAlH4; LiBH4; Charge transfer process; Formaldehyde;
Bond-forming reactions of N22+ with C2H4, C2H6, C3H4 and C3H6
Keywords: انتقال هیدریدها; Dication; Ion-molecule reactions; Hydride transfer; Titan; Reaction dynamics;
Hydride transfer between a phenolic surface pool and reactant paraffins in the catalytic cracking of m-cresol/hexanes mixtures over an HY zeolite
Keywords: انتقال هیدریدها; HY zeolite; m-Cresol; Hexanes; Co-feeding; Phenolic pool; Hydride transfer; Deactivation; Coke formation
Dynamics of the active site architecture in plant-type ferredoxin-NADP+ reductases catalytic complexes
Keywords: انتقال هیدریدها; FNR; ferredoxin-NADP+ reductase; FPR; bacterial-type FNR; AnFNR; FNR from the cyanobacterium Anabaena PCC 7119; PsFNR; FNR from Pisum sativum; XaFPR; FPR from Xanthomonas axonopodis pv. citri; EcFPR; FPR from Escherichia coli; FNRox; FNR in the fully oxid
External loops at the ferredoxin-NADP+ reductase protein-partner binding cavity contribute to substrates allocation
Keywords: انتقال هیدریدها; FNR; ferredoxin-NADP+ reductase; FNRox; FNR in the fully oxidized state; FNRsq; FNR in the partially reduced state; FNRhq; FNR in the anionic hydroquinone (fully reduced) state; Fd; ferredoxin; Fdrd; ferredoxin in the reduced state; dRf; 5-deazariboflavin
Screening of a library of hemisalen ligands in asymmetric H-transfer: Reduction of aromatic ketones in water
Keywords: انتقال هیدریدها; Asymmetric catalysis; Hydride transfer; Hemisalen ligands; Ruthenium; Aromatic ketonesCatalyse asymétrique; Transfert d’hydrure; Ligands hemisalen; Ruthénium; Cétones aromatiques
The C-terminal extension of bacterial flavodoxin-reductases: Involvement in the hydride transfer mechanism from the coenzyme
Keywords: انتقال هیدریدها; FAD and FADHâ; oxidised and two-electron reduced forms of the flavin adenine dinucleotide; WT; wild-type; CTC; charge transfer complex; HT; hydride transfer; ITC; isothermal titration calorimetry; FNR/FPR; plastidic/bacterial ferredoxin-NADP+ reductase;
A hydrogen bond network in the active site of Anabaena ferredoxin-NADP+ reductase modulates its catalytic efficiency
Keywords: انتقال هیدریدها; NADP+; NADPH, nicotinamide-adenine dinucleotide phosphate in its oxidised and reduced forms; FAD; flavin adenine dinucleotide; FNR, FNRox, FNRhq, FNRsq; ferredoxin-NADP+ reductase and FNR in the fully oxidised, anionic hydroquinone (fully reduced) and n
Functionalization of living polyisobutylene: Preference for reduction over electrophilic addition
Keywords: انتقال هیدریدها; Cationic polymerization; Polyisobutylene; Hydride transfer; Silyl hydride
Insights into the isomerization of xylose to xylulose and lyxose by a Lewis acid catalyst
Keywords: انتقال هیدریدها; Aldose–ketose isomerization; Epimerization; Electronic structure calculations; Hydride transfer; Xylose; Xylulose; Lyxose; Biomass
Tryptophan-47 in the active site of Methylophaga sp. strain SK1 flavin-monooxygenase is important for hydride transfer
Keywords: انتقال هیدریدها; Flavin monooxygenases; Active site residue; Flavin; Hydride transfer; Kinetic isotope effects
A systematic study of two complementary protocols allowing the general, mild and efficient deprotection of N-pivaloylindoles
Keywords: انتقال هیدریدها; Protecting groups; Indole; Chemoselectivity; Hydride transfer; Hydrolysis; AOFRVMFRAPUKMS-UHFFFAOYSA-N; NAFAVCAVLHYJBV-UHFFFAOYSA-N; IUOQQFHFSPTAOH-UHFFFAOYSA-N; QVZGKXYWOCDMEP-UHFFFAOYSA-N; GDYNJJAAVMTFPI-UHFFFAOYSA-N;
Characterization of covalent Ene adduct intermediates in “hydride equivalent” transfers in a dihydropyridine model for NADH reduction reactions
Keywords: انتقال هیدریدها; NADH model; Dihydropyridine; Hydride transfer; Ene reaction; Retro-Ene reaction; Ene-adduct; Mechanism; Transition state structure;
On the acid–base properties of Zn–Mg–Al mixed oxides
Keywords: انتقال هیدریدها; Zn–Mg–Al mixed metal oxides; XRD; 27Al MAS NMR; Propan-2-ol elimination reactions; Hydride transfer
On the chemical mechanism of succinic semialdehyde dehydrogenase (GabD1) from Mycobacterium tuberculosis
Keywords: انتقال هیدریدها; Succinic semialdehyde dehydrogenase; Aldehyde dehydrogenase; Chemical mechanism; Stereochemistry; Hydride transfer; Isotope effects;
Manganese substituted Compound I of cytochrome P450 biomimetics: A comparative reactivity study of MnV-oxo versus MnIV-oxo species
Keywords: انتقال هیدریدها; Biomimetic; Porphyrin; Hydroxylation; Hydride transfer; Manganese-oxo; Iron-oxo
Guidelines for tunneling in enzymes
Keywords: انتقال هیدریدها; Electron tunneling; Hydride transfer; Marcus theory; Protein engineering
A variety of electrostatic interactions and adducts can activate NAD(P) cofactors for hydride transfer
Keywords: انتقال هیدریدها; NAD; NADP; Adduct; Hydride transfer; Enzyme activation; Electrostatic interactions
Effect of a conservative mutation of an active site residue involved in substrate binding on the hydride tunneling reaction catalyzed by choline oxidase
Keywords: انتقال هیدریدها; Choline oxidase; Flavoprotein oxidase; Hydride transfer; Hydride tunneling; Kinetic isotope effects; Temperature effects; Flavoprotein;
Reactions of the dications C7H62+, C7H72+, and C7H82+ with methane: Predominance of doubly charged intermediates
Keywords: انتقال هیدریدها; Bond-forming reactions; Dications; DFT calculations; Hydride transfer; Mass spectrometry;
Singlet and triplet state dynamics of charge and hydride transfer reactions of OD+ (X3Σ−) with propyne
Keywords: انتقال هیدریدها; Ion–molecule reactions; Charge transfer; Hydride transfer; Potential energy surfaces; Intersystem crossing
Coenzyme binding and hydride transfer in Rhodobacter capsulatus ferredoxin/flavodoxin NADP(H) oxidoreductase
Keywords: انتقال هیدریدها; FNR; plastidic ferredoxin NADP(H) oxidoreductase; FPR; bacterial ferredoxin/flavodoxin NADP(H) oxidoreductase; Ferredoxin(flavodoxin)-NADP(H) oxidoreductase; Rhodobacter capsulatus; Hydride transfer; Coenzyme binding; NADP+-complex structure;
Comparison of zeolites LaX and LaY as catalysts for isobutane/2-butene alkylation
Keywords: انتقال هیدریدها; Acidity; Hydride transfer; MAS NMR; Lanthanum; Brønsted acid site; Alkylation; Ion exchange
Effective thermal oxidation of isopropanol by an NAD+ model
Keywords: انتقال هیدریدها; Alcohol oxidation; NAD+ model; Acridinium cation; Hydride transfer; Kinetics;
DFT calculations of the alkylation reaction mechanisms of isobutane and 2-butene catalyzed by Brönsted acids
Keywords: انتقال هیدریدها; Alkylation; Addition reaction; Hydride transfer; Molecular simulation
Catalytic mechanism of hydride transfer between NADP+/H and ferredoxin-NADP+ reductase from Anabaena PCC 7119
Keywords: انتقال هیدریدها; Ferredoxin-NADP+ reductase; Hydride transfer; Stopped-flow; Spectra deconvolution
The Crystal Structure of the Bifunctional Deaminase/Reductase RibD of the Riboflavin Biosynthetic Pathway in Escherichia coli: Implications for the Reductive Mechanism
Keywords: انتقال هیدریدها; RP5, ribose-5-phosphate; DHFR, dihydrofolate reductase; EC, E.coli; Bc, B.subtilis; MjaRED, M.jannaschii reductasebi-functional deaminase/reductase; riboflavin biosynthesis; 3D-structure comparison; NADPH; hydride transfer
Alcoholysis of gauche-1,2-(η3-Cp)2W2(NMe2)4: Structural evidence for WW bond cleavage and proton transfer to bound cyclopentadiene
Keywords: انتقال هیدریدها; Ditungsten; Alcoholysis; Dimethylamide; Hydride transfer; WâW bond cleavage;
Alkyl phosphines promoted reductive coupling of acyl cyanides: formation of O-acyl cyanohydrins
Keywords: انتقال هیدریدها; Acyl cyanide; Alkyl phosphine; Cyanohydrins; Hydride transfer; Deuterium labeling experiment;
Production of alkylated gasoline using ionic liquids and immobilized ionic liquids
Keywords: انتقال هیدریدها; Alkylated gasoline; Raffinate II; Ionic liquid; Immobilized ionic liquids; Isobutane alkylation; Hydride transfer
A density functional theory study of the alkylation of isobutane with butene over phosphotungstic acid
Keywords: انتقال هیدریدها; Heteropolyacid; Polyoxometalate; HPA; Alkylation; Solid acid; Hydride transfer; Deactivation; DFT; Quantum chemical
Catalytic cracking and coking of (cyclo)alkane/1-octene mixtures on an equilibrium catalyst
Keywords: انتقال هیدریدها; Catalytic cracking; (Cyclo)alkanes; Alkenes; Hydride transfer; Coke; Coke content; Deactivation
Ion/neutral complexes generated during unimolecular fragmentation: Intra-complex hydride abstraction by tert-butyl cations from electron-rich and electron-poor 1,3-diphenylpropanes
Keywords: انتقال هیدریدها; Ion/neutral complexes; Hydride transfer; Proton transfer; Carbenium ions; Arenium ions
Synthesis of ene-allenes via palladium-catalyzed hydride-transfer reaction of propargylic amines under mild conditions
Keywords: انتقال هیدریدها; Allene; Palladium catalyst; Propargylic amines; Hydride transfer;
Stereo-specificity for pro-(R) hydrogen of NAD(P)H during enzyme-catalyzed hydride transfer to CL-20
Keywords: انتقال هیدریدها; CL-20; Clostridium sp.; Dehydrogenase; Diaphorase; Hydride transfer;