کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10145307 | 1646359 | 2019 | 30 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Development of a supramolecular accelerator simultaneously to increase the cross-linking density and ductility of an epoxy resin
ترجمه فارسی عنوان
توسعه یک شتاب دهنده سوپر مولکولی به طور همزمان برای افزایش چگالی متقابل و انعطاف پذیری یک رزین اپوکسی
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
The development of a novel accelerator capable of simultaneously enhancing the cross-linking density and ductility of an epoxy resin without sacrificing the reaction rate is reported. The basic concept comprises the synthesis of a tertiary amine-functionalized polyrotaxane (PRX_NR1) accelerator: a molecular necklace structure that induces a high cross-linking density as well as active molecular movement. Fourier transform infrared spectroscopy and differential scanning calorimetry measurements confirmed that the PRX_NR1-containing epoxy resin afforded a high reaction rate. Furthermore, the cross-linking density and mechanical properties of the epoxy resin were confirmed by dynamic mechanical analysis and tensile testing. Consequently, the PRX_NR1-containing epoxy resin greatly increased the cross-linking density, thereby resulting in an increase in tensile strength and glass transition temperature. Interestingly, the epoxy resin exhibited a simultaneous increase in ductility which is important to avoid brittle fracture (low toughness) of the epoxy resins. These results indicate that the proposed molecular necklace-like supramolecular PRX_NR1 accelerator is highly effective to overcome the traditional drawbacks of an epoxy resin that pose significant problems in the industrial field.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 356, 15 January 2019, Pages 303-311
Journal: Chemical Engineering Journal - Volume 356, 15 January 2019, Pages 303-311
نویسندگان
Jiae Seo, Nobuhiko Yui, Ji-Hun Seo,