کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10156035 | 1666370 | 2019 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Achieving quick charge/discharge rate of 3.0â¯Vâ¯sâ1 by 2D titanium carbide (MXene) via N-doped carbon intercalation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The MXenes with excellent chemical and physical properties are novel and promising electrode materials for supercapacitors. However, aggregation and restacking of MXene sheets limit material's electrochemical performance. Here, we report a method to prevent MXene sheets from restacking and significantly improved electrochemical capability of Ti3C2Tx MXene by intercalating with N-doped carbon (NC) introduced from ZIF-8. Ti3C2Tx MXene sheets were prepared by etching Ti3AlC2 powder in HF, then ZIF-8/Ti3C2Tx composite was prepared, followed by annealing in H2/Ar atmosphere. Benefited from higher specific surface area and electron conductivity, the obtained NC-Ti3C2Tx hybrid shows the quick charge/discharge rate up to 3.0â¯Vâ¯sâ1, little IR drop at 50.0 A gâ1, higher specific capacitance of 82.8â¯Fâ¯gâ1 at 1.0â¯Aâ¯gâ1 (about 210% of the origin), and 100% retention in capacitance after 5000 cycles. This new and effective approach efficiently enhanced the electrochemical performance of Ti3C2Tx MXenes and improved them as one of auspicious electrode materials in future energy storage devices.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 234, 1 January 2019, Pages 21-25
Journal: Materials Letters - Volume 234, 1 January 2019, Pages 21-25
نویسندگان
Cheng Zhang, Liang Wang, Wu Lei, Yuting Wu, Caiwei Li, Muhammad Asim Khan, Yu Ouyang, Xinyan Jiao, Haitao Ye, Sadaf Mutahir, Qingli Hao,