کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10245103 47713 2005 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Combined in situ attenuated total reflection infrared and UV-vis spectroscopic study of alcohol oxidation over Pd/Al2O3
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Combined in situ attenuated total reflection infrared and UV-vis spectroscopic study of alcohol oxidation over Pd/Al2O3
چکیده انگلیسی
In situ attenuated total reflection (ATR) infrared and UV-vis spectroscopy are combined to yield simultaneous time-resolved information on dissolved reaction products, adsorbed species, and the catalyst during the oxidation of ethanol and 2-propanol on a 5% Pd/Al2O3 catalyst. The oxidation is initiated by change from hydrogen- to oxygen-saturated solvent flow. 2-Propanol oxidation is observed only in the transient period, whereas ethanol oxidation is also observed in the steady state. This may be ascribed to overoxidation of the catalyst in the former case. In a mixture of the two alcohols the same thing is observed. Competitive adsorption in the steady state may explain this behavior. For ethanol oxidation ethyl acetate is also observed during the transient period. The UV-vis spectra reveal a fast reversible change of the catalyst with switching between hydrogen and oxygen and a slow irreversible change during ethanol oxidation. The latter is ascribed to the change in Pd particle structure, which hardly affects, however, catalyst activity on the time scale of about 1 h.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 229, Issue 1, 1 January 2005, Pages 55-63
نویسندگان
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