کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10275725 | 463387 | 2005 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of ligand protonation on the facilitated ion transfer reactions across oil|water interfaces. II. Complex formation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Effect of ligand protonation on the facilitated ion transfer reactions across oil|water interfaces. II. Complex formation Effect of ligand protonation on the facilitated ion transfer reactions across oil|water interfaces. II. Complex formation](/preview/png/10275725.png)
چکیده انگلیسی
In a previous paper [J. Electroanal. Chem. 578 (2005) 159] we have presented the general equations for a model of ion transfer reactions across the oil|water interface assisted by a neutral protonatable ligand. Our analysis focused mainly on the effect of water autoprotolysis on transfer processes. In this second part, cation transfer assisted by a protonatable ligand is described. The competitive reaction for a ligand between metal cation and proton is presented. The results are analyzed for different zones determined by the cation/ligand and proton/ligand concentration ratios.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 585, Issue 2, 15 November 2005, Pages 256-268
Journal: Journal of Electroanalytical Chemistry - Volume 585, Issue 2, 15 November 2005, Pages 256-268
نویسندگان
S.A. Dassie,