کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10276076 | 463416 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical study of catechols in the presence of 4,6-dihydroxy-2-methylpyrimidine
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Electrochemical oxidation of catechol (1a), 3-methylcatechol (1b), and 3-methoxycatechol (1c) has been studied in the presence of 4,6-dihydroxy-2-methylpyrimidine (3) as a nucleophile in aqueous solution using cyclic voltammetry and controlled-potential coulometry. The results indicate that the quinones derived from catechols (1a-1c) participate in Michael addition reactions with 3 to form the corresponding benzofuro[2,3-d]pyrimidine derivatives (6a-6c). The electrochemical synthesis of (6a-6c) has been successfully performed in an undivided cell in good yield and purity. The mechanism of oxidation was deduced from voltammetric data and by coulometry at controlled-potential. The products have been characterized after purification by IR, 1H NMR, 13C NMR and MS.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 577, Issue 2, 1 April 2005, Pages 205-210
Journal: Journal of Electroanalytical Chemistry - Volume 577, Issue 2, 1 April 2005, Pages 205-210
نویسندگان
Ali Reza Fakhari, Davood Nematollahi, Abdolmajid Bayandori Moghaddam,