کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10276300 463424 2005 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
How does the double layer at a disk electrode charge?
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
How does the double layer at a disk electrode charge?
چکیده انگلیسی
Because of the nonuniform accessibility of its surface to ion transport from the solution, the double layer at an inlaid disk electrode charges anomalously in response to a potential step. A numerical simulation of the problem shows that the overall current versus time transient differs little from that for a single resistor in series with a single capacitor. Nevertheless, the charging process, away from the disk's perimeter, differs surprisingly from what might be expected in that the current density initially increases with time.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 575, Issue 1, 15 January 2005, Pages 81-93
نویسندگان
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