کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10279733 | 465421 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Microstructure, rheology and dewatering behaviour of smectite dispersions during orthokinetic flocculation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Microstructure, rheology and dewatering behaviour of smectite dispersions during orthokinetic flocculation Microstructure, rheology and dewatering behaviour of smectite dispersions during orthokinetic flocculation](/preview/png/10279733.png)
چکیده انگلیسی
The influence of high molecular weight (>7.5 Ã 106 Da) polyacrylamide (PAM) flocculant type (anionic vs non-ionic), solution speciation (KNO3 + CaCl2 vs KNO3) and shear on microstructure, rheology and the dewatering behaviour of Na-exchanged smectite clay dispersions has been investigated under orthokinetic flocculation conditions at pH 7.5. Massive osmotic swelling, accompanied by high shear yield stress and non-settling behaviour, were displayed by dispersions prepared in 10â3 M KNO3 background electrolyte and to which 0.05 M CaCl2 was subsequently added. Prior clay dispersion in CaCl2-based solution however led to rapid exchange of Ca2+ with Na+ in the clay and suppression of swelling which reflected in low yield stress, dramatic reduction in particle zeta potential and marginally improved dewaterability. Cryo-SEM image analysis indicated the presence of highly networked “honeycomb” structure in the swelling clay pulps and loosely networked, chain-like structure in non-swelling dispersions. Dewatering of suppressed swelling pulps indicated optimum conditions for orthokinetic flocculation, dependent upon flocculant structure type and shear intensity, which strongly influenced the settling rate but not the low pulp consolidation (â¼21 wt% solid) behaviour. Under optimum conditions, anionic PAM produced significantly faster settling flocs than non-ionic PAM at up to 500 g polymer tâ1 solid. Post-sedimentation shear action markedly improved pulp solid loading by 5-7 wt%, independent of PAM type. Anionic PAM flocculated pulps displayed 25% higher yield stresses than non-ionic PAM-based pulps. Upon shear however, the yield stress of the former decreased dramatically to values lower than those of the latter, indicating that anionic PAM-based flocs structures were less robust, a finding which is consistent with cryo-SEM imaging.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Minerals Engineering - Volume 18, Issue 12, October 2005, Pages 1173-1182
Journal: Minerals Engineering - Volume 18, Issue 12, October 2005, Pages 1173-1182
نویسندگان
A. McFarlane, K. Bremmell, J. Addai-Mensah,