کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10386107 | 882866 | 2010 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Construction of barium (II) PVC membrane electrochemical sensor based on 3-deoxy-d-erythro-hexos-2-ulose bis (thiosemicarbazone) as a novel ionophore
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this study, a new ion-selective electrode for Ba2+ is described, illustrating 3-deoxy-d-erythro-hexos-2-ulose bis (thiosemicarbazone) (DHUT) in a poly(vinylchloride) (PVC) membrane with benzyl acetate (BA) as a plasticizer and sodium tetraphenyl borate (NaTPB) as an anionic additive. This sensor presented very good selectivity and sensitivity towards the Ba2+ ions over a wide variety of cations, including alkali, alkaline earth, transition and heavy metal ions. The electrode revealed a great improvement in the selectivity coefficients for the Ba2+ ions in comparison with the formerly reported Ba2+ sensors. The proposed electrode exhibited a significantly enhanced response towards the Ba2+ ions across the concentration range of 1.0 Ã 10â 6-1.0 Ã 10â 2 M for the pH variation from 2.6 to 11 with a lower detection limit of 5.6 Ã 10â 7 M. Moreover, the sensors displayed the Nernstian slope of 29.6 ± 0.5 mV per decade, having a fast response time within 15 s over the entire concentration range. It could also be used for at least 2 months with no potential divergence. As a result, the developed sensor was successfully applied to the direct barium ion determination in solutions, rock samples and as an indicator electrode in the Ba2+ ion potentiometric titration with EDTA.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Desalination - Volume 250, Issue 1, 1 January 2010, Pages 56-61
Journal: Desalination - Volume 250, Issue 1, 1 January 2010, Pages 56-61
نویسندگان
Hassan Ali Zamani, Mohammad Taghi Hamed-Mosavian, Elham Aminzadeh, Mohammad Reza Ganjali, Mousa Ghaemy, Hossien Behmadi, Farnoush Faridbod,