کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10398093 | 889934 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
New bipyrazolic derivatives as corrosion inhibitors of steel in 1Â M HCl
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تکنولوژی و شیمی فرآیندی
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چکیده انگلیسی
The inhibition of corrosion of steel in molar hydrochloric acid solution by two bipyrazolic compounds is studied by weight loss and electrochemical polarisation measurements. The two methods give consistent results. The polarisation curves indicate that the bipyrazolic compounds act as mixed-type inhibitors. These compounds are efficient inhibitors. The inhibition efficiency increases with the increase of inhibitor concentration to reach 96 and 92% at 5Â ÃÂ 10â4Â M for Bipyr 1 and Bipyr 2, respectively. The temperature effect on the corrosion behaviour of steel in 1Â M HCl with and without the bipyrazolic compounds at 5Â ÃÂ 10â4Â M is studied in the temperature range from 308 to 353Â K. The adsorption of inhibitors on the steel surface is found to obey the Frumkin adsorption isotherm model. From the adsorption isotherm, some thermodynamic data for the adsorption process (f, K and ÎGadsâ) are calculated and discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Progress in Organic Coatings - Volume 54, Issue 3, 1 November 2005, Pages 170-174
Journal: Progress in Organic Coatings - Volume 54, Issue 3, 1 November 2005, Pages 170-174
نویسندگان
K. Tebbji, A. Aouniti, M. Benkaddour, H. Oudda, I. Bouabdallah, B. Hammouti, A. Ramdani,